Epoxy-Anhydride Binders with Phosphonium Catalyst for Fabrication of Products from Composition Materials through Pressure Impregnation

被引:1
作者
Khamidullin O.L. [1 ]
Amirova L.R. [2 ]
Andrianova K.A. [1 ,2 ]
Amirova L.M. [1 ,2 ]
机构
[1] Kazan National Research Technical University, Kazan, 420111, Tatarstan
[2] Kazan Federal University, Kazan, 420111, Tatarstan
关键词
anhydride hardener; degree of conversion; epoxy resins; gel time; glass transition temperature; phosphonium catalyst;
D O I
10.1134/S2075113320010190
中图分类号
学科分类号
摘要
Abstract: Process advantages of phosphonium salt as a catalyst of epoxy compositions have been demonstrated and the characteristics of low-viscous epoxy-anhydride binders on its basis have been studied. The possibility of controlling the gel time of epoxy-anhydride compositions by using various concentrations of phosphonium catalyst has been shown. It has been determined that the binders with phosphonium salts possessing high working life at low temperatures exhibit higher activity than 2-methylimidazole at identical concentration of catalyst. © 2020, Pleiades Publishing, Ltd.
引用
收藏
页码:79 / 84
页数:5
相关论文
共 18 条
[1]  
Lee H., Neville K., Handbook of Epoxy Resins, (1967)
[2]  
Paken A.M., Epoksidnye Soedineniya I Epoksidnye Smoly (Epoxy Compounds and Epoxy Resins), (1962)
[3]  
Chernin I.Z., Smekhov F.M., Zherdev Y.V., (Epoxy Polymers and Compositions), (1982)
[4]  
Bobylev V.A., Hardeners of epoxy resins, Kompoz. Mir, 4, 7, pp. 20-24, (2006)
[5]  
Fedoseev M.S., Derzhavinskaya L.F., Improving the heat resistance of epoxy-anhydride polymers using imidazoles, Fiz.-Khim. Polim.: Sint., Svoistva Primen., 15, pp. 222-227, (2009)
[6]  
Amirova L.R., Burilov A.R., Amirova L.M., Bauer I., Habicher W.D., Kinetics and mechanistic investigation of epoxy–anhydride compositions cured with quaternary phosphonium salts as accelerators, J. Polym. Sci., Part A: Polym. Chem., 54, pp. 1088-1097, (2016)
[7]  
Amirova L.R., Khamidullin O.L., Zalyalova G.M., Amirova L.M., Estimation of kinetic parameters for curing of epoxy-anhydride compositions by DSC, Russ. Chem. Bull., 66, pp. 483-487, (2017)
[8]  
Khamidullin O.L., Amirova L.R., Gadyeva I.I., Dimiev A.M., Amirova L.M., (2018)
[9]  
Flores H.A., On the cure kinetics modeling of epoxy-anhydride systems used in glass reinforced pipe production, Thermochim. Acta, 573, pp. 1-9, (2013)
[10]  
Leena K., Soumyamol P.B., Baby M., Suraj S., Rajeev R., Mohan D.S., Non-isothermal cure and decomposition kinetics of epoxy-imidazole systems, J. Therm. Anal. Calorim., 130, pp. 1053-1061, (2017)