Enthalpies of formation of acetyl radicals

被引：0
作者：
Yu. D. Orlov
E. M. Chernova
M. Yu. Orlov
V. V. Turovtsev
机构：
[1] Tver State University,
[2] Tver State Medical Academy,undefined
来源：
Russian Journal of Physical Chemistry A | 2013年 / 87卷
关键词：
free radicals; enthalpy of formation; structure-property relationship; additive group approach;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The database on the enthalpies of formation (ΔfH○) of aliphatic acetyl radicals of the RC·(O) type is analyzed and extended. ΔfH○ values are estimated for the first time for three compounds on the basis of experimental data. The data were analyzed using the additive group approach with the determination and correction of parameters. Good correspondence between the ΔfH○(RC·(O)) values calculated according to parameters with experimental data is observed.
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页码：1607 / 1610
页数：3
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