Hyperbranched polyester poly[3-(morpholin-4-yl)propionates] and their copper(II) complexes

被引：0
作者：
A. R. Gataulina
E. M. Khasanova
A. S. Basalaev
N. A. Ulakhovich
G. A. Kutyrev
S. V. Yurtaeva
M. P. Kutyreva
机构：
[1] Kazan (Volga region) Federal University,Butlerov Institute of Chemistry
[2] Kazan National Research Technological University,Zavoiskii Physical
[3] Russian Academy of Sciences,Technical Institute
来源：
Russian Journal of General Chemistry | 2017年 / 87卷
关键词：
hyperbranched polyester poly[3-(morpholin-4-yl)propionates]; copper(II) complexes; ionization; complex formation; electronic absorption spectroscopy;
D O I：
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摘要：
Novel polydentate ligands on the basis of second- and third-generation hyperbranched polyesters containing terminal poly[3-(morpholin-4-yl)propionate] groups and their 6 : 1 and 13 : 1 polynuclear copper(II) complexes were synthesized. The degree of functionalization of the polyesters with morpholine increases in going from the second (56%) to third generation (68%). According to IR and electronic spectroscopy data, each coordination entity in the complexes is an isolated paramagnetic center of the formula CuN2O2Solv2 (Solv = H2O, DMSO).
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页码：1995 / 2005
页数：10
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