Effect of the structure of phenols on their activity in the reaction with ethylbenzene peroxy radicals

被引：0
|
作者：
Belaya N.I. [1 ]
Ovcharova O.Y. [1 ]
Nikolaevskii A.N. [1 ]
Filippenko T.A. [1 ]
Zaets V.A. [1 ]
机构：
[1] Donets'k National University, 83055 Donets'k
来源：
Theoretical and Experimental Chemistry | 2004年 / 40卷 / 4期
关键词：
Antioxidant; Ethylbenzene; Inhibition; Oxidation; Peroxy radical; Phenol;
D O I：
10.1023/B:THEC.0000041808.06992.b2
中图分类号：
学科分类号：
摘要：
In a study of the reactivity of sterically protected phenols in the reaction with ethylbenzene peroxy radicals as a function of their molecular structure and as compared with unprotected phenols, we have established the major characteristic features of the structure-antioxidant activity relation for phenols of different structures. ©2004 Springer Science+Business Media, Inc.
引用
收藏
页码：234 / 240
页数：6
相关论文
共 50 条
  • [21] Rate constants for the reaction of NO and HO2 with peroxy radicals formed from the reaction of OH, Cl or NO3 with alkenes, dienes and α, β-unsaturated carbonyls
    King, MD
    Thompson, KC
    ATMOSPHERIC ENVIRONMENT, 2003, 37 (32) : 4517 - 4527
  • [22] Thermodynamics, kinetics and structure-activity relationship of hydroxyanthraquinones scavenging free radicals
    Wang, Yunxiao
    Liu, Chang
    Tang, Shanshan
    Tian, Jing
    Wang, Yi
    Yang, Yi
    FOOD BIOSCIENCE, 2023, 53
  • [23] Nickel substituted copper chromite spinels: Preparation, characterization and catalytic activity in the oxidation reaction of ethylbenzene
    George, Kochurani
    Sugunan, S.
    CATALYSIS COMMUNICATIONS, 2008, 9 (13) : 2149 - 2153
  • [24] Ozonation of phenol and substituted phenols: Dependency of the reaction rate constant on the molecular structure
    Bhosale, Ghanshyam S.
    Vaidya, Prakash D.
    Gogate, Parag R.
    Joshi, Jyeshtharaj B.
    Patil, Raosaheb N.
    CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 2022, 100 (02) : 317 - 324
  • [25] A quantitative structure activity relationship (QSAR) model for predicting the rate constant of the reaction between VOCs and NO3 radicals
    Liu, Yawei
    Cheng, Zhiwen
    Liu, Shiqiang
    Ren, Yuanyang
    Yuan, Tao
    Zhang, Xuxiang
    Fan, Maohong
    Shen, Zhemin
    CHEMICAL ENGINEERING JOURNAL, 2022, 448
  • [26] Cobalt-containing hexagonal mesoporous molecular sieves (Co-HMS): Synthesis, characterization and catalytic activity in the oxidation reaction of ethylbenzene
    Bhoware, Shrikant S.
    Shylesh, S.
    Kamble, K. R.
    Singh, A. P.
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2006, 255 (1-2) : 123 - 130
  • [27] Revisiting the scavenging activity of glutathione: Free radicals diversity and reaction mechanisms
    Luque-Ceballos, Jonathan C.
    Rodriguez-Zamora, Penelope
    Lopez-Olivos, Juan Carlos
    Garzon, Ignacio L.
    COMPUTATIONAL AND THEORETICAL CHEMISTRY, 2023, 1227
  • [28] Formation of highly oxidized multifunctional compounds: autoxidation of peroxy radicals formed in the ozonolysis of alkenes - deduced from structure-product relationships
    Mentel, T. F.
    Springer, M.
    Ehn, M.
    Kleist, E.
    Pullinen, I.
    Kurten, T.
    Rissanen, M.
    Wahner, A.
    Wildt, J.
    ATMOSPHERIC CHEMISTRY AND PHYSICS, 2015, 15 (12) : 6745 - 6765
  • [29] Polyoxometalate (POM) oxidation of phenols: Effect of aromatic substituent groups on reaction mechanism
    Kim, Yong Sik
    Chang, Hou-min
    Kadla, John F.
    JOURNAL OF WOOD CHEMISTRY AND TECHNOLOGY, 2008, 28 (01) : 1 - 25
  • [30] DPPH Measurements and Structure-Activity Relationship Studies on the Antioxidant Capacity of Phenols
    Yamauchi, Moeka
    Kitamura, Yukino
    Nagano, Haruka
    Kawatsu, Junya
    Gotoh, Hiroaki
    ANTIOXIDANTS, 2024, 13 (03)
12345