Theory of nematic ordering in supramolecular systems: Self-assembly of mesogenic groups and self-organization of the system

被引:0
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作者
T. M. Birshtein
V. M. Amoskov
E. O. Smirnov
机构
[1] Russian Academy of Sciences,Institute of Macromolecular Compounds
来源
Polymer Science Series A | 2016年 / 58卷
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摘要
The behaviors of two systems are considered: a low-molecular system (a binary mixture of low-molecular components) and a polymer system (mixture of a macromolecules and a low-molecular dopant) whose components reversibly bind to form dimers capable of liquid-crystal ordering. The general theory of binary-mixture structuring, where two processes occur—self-assembly of mesogenic dimers of the mixture components and their self-organization—is presented. The theory demonstrates general laws of the behavior of low-molecular and polymer systems as well as differences related to the features of polymer thermodynamics.
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页码:593 / 605
页数:12
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