Physicochemical study of binuclear copper(II), oxovanadium(IV), and iron(III) complexes with bis-1′-phthalazinylhydrazone of 2,6-diformyl-4-tert-butylphenol

被引：0

作者：

L. D. Popov

S. I. Levchenkov

I. N. Shcherbakov

Yu. P. Tupolova

A. A. Zubenko

I. E. Melkozerova

V. V. Lukov

V. A. Kogan

机构：

[1] Southern Federal University,

[2] Southern Scientific Center of Russian Academy of Sciences,undefined

[3] North-Caucasus Regional Research Veterinary Institute,undefined

来源：

Russian Journal of General Chemistry | 2010年 / 80卷

关键词：

General Chemistry; Hydrazone; Differential Pulse Voltammetry; Oxovanadium; Physicochemical Study;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Binuclear copper(II), oxovanadium(IV), and iron(III) complexes with bis-1′-phthalazinylhydrazone of 2,6-diformyl-4-tert-butylphenol have been prepared. An antiferromegnetic exchange interaction between the paramagnetic centers was found. Redox properties of the complexes were studied by the methods of cyclic and differential pulse voltammetry; the reduction of Cu(II) complexes was shown to proceed in two consecutive one-electron steps.

引用

页码：1853 / 1859

页数：6

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