Physicochemical study of binuclear copper(II), oxovanadium(IV), and iron(III) complexes with bis-1′-phthalazinylhydrazone of 2,6-diformyl-4-tert-butylphenol

被引：0
|
作者：
L. D. Popov
S. I. Levchenkov
I. N. Shcherbakov
Yu. P. Tupolova
A. A. Zubenko
I. E. Melkozerova
V. V. Lukov
V. A. Kogan
机构：
[1] Southern Federal University,
[2] Southern Scientific Center of Russian Academy of Sciences,undefined
[3] North-Caucasus Regional Research Veterinary Institute,undefined
来源：
Russian Journal of General Chemistry | 2010年 / 80卷
关键词：
General Chemistry; Hydrazone; Differential Pulse Voltammetry; Oxovanadium; Physicochemical Study;
D O I：
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学科分类号：
摘要：
Binuclear copper(II), oxovanadium(IV), and iron(III) complexes with bis-1′-phthalazinylhydrazone of 2,6-diformyl-4-tert-butylphenol have been prepared. An antiferromegnetic exchange interaction between the paramagnetic centers was found. Redox properties of the complexes were studied by the methods of cyclic and differential pulse voltammetry; the reduction of Cu(II) complexes was shown to proceed in two consecutive one-electron steps.
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页码：1853 / 1859
页数：6
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