Copolymers of N-Methyl-N-vinylacetamide with Allylidene Diacetate

被引：0
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作者：
I. I. Gavrilova
O. N. Zhuravskaya
E. F. Panarin
机构：
[1] Russian Academy of Sciences,Institute of Macromolecular Compounds
来源：
Russian Journal of Applied Chemistry | 2018年 / 91卷
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摘要：
New random copolymers containing protected aldehyde groups were prepared by radical copolymerization of N-methyl-N-vinylacetamide with allylidene diacetate. The relative activity constants were determined: for N-methyl-N-vinylacetamine, r1 = 1.02 ± 0.015; for allylidene acetate, r2 = 0.95 ± 0.02. Removal of the acetyl protecting groups by base hydrolysis of allylidene diacetate units at 45–50°С yielded water-soluble N-methyl-Nvinylacetamide copolymers with high content of acrolein units, promising for use as polymer carriers of biologically active compounds.
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页码：1025 / 1028
页数：3
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