Hydrogenation of carbon dioxide in the presence of rhodium catalysts

被引：0

作者：

N. V. Kolesnichenko

N. N. Ezhova

E. V. Kremleva

E. V. Slivinskii

机构：

[1] Russian Academy of Sciences,A. V. Topchiev Institute of Petrochemical Synthesis

[2] Russian Academy of Sciences,Institute of High Temperatures

来源：

Russian Chemical Bulletin | 2004年 / 53卷

关键词：

hydrogenation; carbon dioxide; formic acid; methanol; triphenylphosphine;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The results of CO2 hydrogenation in the presence of the Wilkinson complexes, viz., RhCl3 and acacRh(CO)2, at room temperature and excess PPh3 are presented. The influence of different ions on the catalytic properties of the Rh complexes was studied. Methanol and methyl formate are formed along with formic acid in the presence of an inorganic salt. Ions that are the most active in the formation of formic acid are the least active in methanol formation.

引用

页码：2542 / 2545

页数：3

共 50 条

[41] Rhodium catalysts promoted by cerium oxide in the CO2 hydrogenation to ethanol [J].

Kusama, H ;

Okabe, K ;

Sayama, K ;

Arakawa, H .

SEKIYU GAKKAISHI-JOURNAL OF THE JAPAN PETROLEUM INSTITUTE, 1999, 42 (03) :178-179

[42] Active Sites and Structure-Activity Relationships of Copper-Based Catalysts for Carbon Dioxide Hydrogenation to Methanol [J].

Natesakhawat, Sittichai ;

Lekse, Jonathan W. ;

Baltrus, John P. ;

Ohodnicki, Paul R., Jr. ;

Howard, Bret H. ;

Deng, Xingyi ;

Matranga, Christopher .

ACS CATALYSIS, 2012, 2 (08) :1667-1676

[43] Hydrogenation of carbon dioxide on cobalt catalysts - activation, deactivation, influence of carbon monoxide [J].

Kestel, Ulrich, 1600, VCH Verlagsgesellschaf mbH, Weinheim, Germany (17)

[44] Nickel-Containing Catalysts Based on Rice Husk for Hydrogenation of Carbon Dioxide to Methane [J].

Rodin, V. Yu. ;

Novotortsev, R. Yu. ;

Magdalinova, N. A. ;

Savilov, S. V. .

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2025, 99 (06) :1250-1261

[45] Catalytic Hydrogenation of Carbon Dioxide to Methanol: Synergistic Effect of Bifunctional Cu/Perovskite Catalysts [J].

Hus, Matej ;

Kopac, Drejc ;

Likozar, Blaz .

ACS CATALYSIS, 2019, 9 (01) :105-116

[46] EFFECTS OF ADDITION OF CHROMIUM, MANGANESE, OR MOLYBDENUM TO IRON CATALYSTS FOR CARBON-DIOXIDE HYDROGENATION [J].

LEE, MD ;

LEE, JF ;

CHANG, CS ;

DONG, TY .

APPLIED CATALYSIS, 1991, 72 (02) :267-281

[47] Highly efficient hydrogenation of carbon dioxide to methyl formate over supported gold catalysts [J].

Wu, Congyi ;

Zhang, Zhaofu ;

Zhu, Qinggong ;

Han, Hongling ;

Yang, Yingying ;

Han, Buxing .

GREEN CHEMISTRY, 2015, 17 (03) :1467-1472

[48] Hydrogenation of Carbon Dioxide to Methanol by Using a Homogeneous Ruthenium-Phosphine Catalyst [J].

Wesselbaum, Sebastian ;

vom Stein, Thorsten ;

Klankermayer, Juergen ;

Leitner, Walter .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (30) :7499-7502

[49] Hydrogenation and hydroamination in the presence of catalysts based on platinum and carbon nanofibers [J].

Magdalinova, N. A. ;

Klyuev, M. V. .

PETROLEUM CHEMISTRY, 2016, 56 (12) :1123-1127

[50] Hydrogenation and hydroamination in the presence of catalysts based on platinum and carbon nanofibers [J].

N. A. Magdalinova ;

M. V. Klyuev .

Petroleum Chemistry, 2016, 56 :1123-1127

← 1 2 3 4 5 →