Hydrogenation of carbon dioxide in the presence of rhodium catalysts

被引：0
作者：
N. V. Kolesnichenko
N. N. Ezhova
E. V. Kremleva
E. V. Slivinskii
机构：
[1] Russian Academy of Sciences,A. V. Topchiev Institute of Petrochemical Synthesis
[2] Russian Academy of Sciences,Institute of High Temperatures
来源：
Russian Chemical Bulletin | 2004年 / 53卷
关键词：
hydrogenation; carbon dioxide; formic acid; methanol; triphenylphosphine;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The results of CO2 hydrogenation in the presence of the Wilkinson complexes, viz., RhCl3 and acacRh(CO)2, at room temperature and excess PPh3 are presented. The influence of different ions on the catalytic properties of the Rh complexes was studied. Methanol and methyl formate are formed along with formic acid in the presence of an inorganic salt. Ions that are the most active in the formation of formic acid are the least active in methanol formation.
引用
收藏
页码：2542 / 2545
页数：3
相关论文
共 50 条
[31]   Synthesis of lower olefins by hydrogenation of carbon dioxide over supported iron catalysts [J].
Wang, Jingjuan ;
You, Zhenya ;
Zhang, Qinghong ;
Deng, Weiping ;
Wang, Ye .
CATALYSIS TODAY, 2013, 215 :186-193
[32]   Catalytic Hydrogenation of Carbon Dioxide to Formic Acid [J].
Behr, Arno ;
Nowakowski, Kristina .
CO2 CHEMISTRY, 2014, 66 :223-258
[33]   Recent advances in the homogeneous hydrogenation of carbon dioxide [J].
Jessop, PG ;
Joó, F ;
Tai, CC .
COORDINATION CHEMISTRY REVIEWS, 2004, 248 (21-24) :2425-2442
[34]   Preparation of N,N-Dibutylformylamide-Hydrogenation of Carbon Dioxide in Presence of Dibutylamine [J].
Ma, Runzhi ;
Li, Yunqing ;
Zhou, Hongyong ;
Wang, Jiaxi .
CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2009, 29 (11) :1843-1848
[35]   Carbon dioxide hydrogenation over Fe-Ce catalysts [J].
Perez-Alonso, F. J. ;
Ojeda, M. ;
Herranz, T. ;
Rojas, S. ;
Gonzalez-Carballo, J. M. ;
Terreros, P. ;
Fierro, J. L. G. .
CATALYSIS COMMUNICATIONS, 2008, 9 (09) :1945-1948
[36]   HYDROGENATION OF CARBON-DIOXIDE ON IRON-MANGANESE CATALYSTS [J].
KUEI, CK ;
CHEN, WS ;
LEE, MD .
JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 1991, 38 (02) :127-137
[37]   Recent Progress in Heterogeneous Catalysts for the Hydrogenation of Carbon Dioxide to Methanol [J].
Zhou Zixuan ;
Yang Haiyan ;
Sun Yuhan ;
Gao Peng .
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2022, 43 (07)
[38]   Electroreduction of Carbon Dioxide to Formate by Homogeneous Ir Catalysts in Water [J].
Kanega, Ryoichi ;
Onishi, Naoya ;
Wang, Lin ;
Himeda, Yuichiro .
ACS CATALYSIS, 2018, 8 (12) :11296-11301
[39]   Hydrogenation of Carbon Dioxide Using Half-Sandwich Cobalt, Rhodium, and Iridium Complexes: DFT Study on the Mechanism and Metal Effect [J].
Hou, Cheng ;
Jiang, Jingxing ;
Zhang, Shidong ;
Wang, Guo ;
Zhang, Zhihan ;
Ke, Zhuofeng ;
Zhao, Cunyuan .
ACS CATALYSIS, 2014, 4 (09) :2990-2997
[40]   Developing indium-oxide based catalysts for efficient hydrogenation of carbon dioxide to methanol: a mini-review [J].
Wang, Yuxin ;
Yang, Na ;
Wang, Zeshan ;
Tian, Dong ;
Wang, Hua ;
Li, Kongzhai .
FRONTIERS OF CHEMICAL SCIENCE AND ENGINEERING, 2025, 19 (03)
12345