Effect of Oxygen Sputter Pressure on the Structural, Morphological and Optical Properties of ZnO Thin Films for Gas Sensing Application

被引:9
作者
Fairose S. [1 ]
Ernest S. [1 ]
Daniel S. [2 ]
机构
[1] PG & Research Department of Physics, Urumu Dhanalakshmi College, Trichy, 620 019, Tamil Nadu
[2] PG & Research Department of Physics, Bharathidasan University, Trichy, 620 024, Tamil Nadu
来源
Sensing and Imaging | 2018年 / 19卷 / 01期
关键词
Ammonia; Chemiresistor; Sensitivity; Sputtering;
D O I
10.1007/s11220-017-0184-5
中图分类号
学科分类号
摘要
ZnO thin films were prepared on glass substrates at low (5 × 10−4 mbar) and high (3 × 10−3 mbar) sputter pressure using dc reactive magnetron sputtering. The structural, morphological, compositional and optical properties of the thin films were investigated. XRD patterns of both films confirmed the polycrystalline nature of the films with hexagonal Wurtzite structure. SEM study indicates that the surface of the film formed at high sputter pressure was more uniform, compact and porous in nature. From the EDAX analysis, no other characteristic peaks of other impurities were observed and the formation of single phase of ZnO was confirmed. From the study of photoluminescence, three peaks were observed, one strong near band-edge emission at 390 nm followed by weak and broad visible emissions around 420–480 nm. Room temperature ammonia sensing characteristics of ZnO nanothin films formed at higher sputter pressure were studied for different ammonia vapour concentration levels. The response of the Ammonia sensor at room temperature (30 °C) operation was observed to be of high sensitivity with quick response and recovery times. © 2017, The Author(s).
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共 59 条
[1]  
Bhalla A., Mahi S., Sharma N., Singh S., Glycopyrrolate in toxic exposure to ammonia gas, Journal of Emergencies, Trauma and Shock, 4, 1, pp. 140-141, (2011)
[2]  
Moss M., Safety of beef processing method is questioned, (2009)
[3]  
Leung C.M., Foo C.L., Mass ammonia inhalation burns—Experience in the management of patients, Annals of the Academy of Medicine, Singapore, 21, pp. 624-629, (1992)
[4]  
Smeets M.A.M., Bulsing P.J., van Rooden S., Steinmann R., de Ru J.A., Ogink N.W.M., van Thriel C., Dalton P.H., Odor and irritation thresholds for ammonia: A comparison between static and dynamic olfactometry odor and irritation thresholds for ammonia, Chemical Senses. Advance Access Published September, 26, (2006)
[5]  
De la Hoz R.E., Schueter D.P., Rom W.N., Chronic lung disease secondary to ammonia inhalation injury: A report on three cases, American Journal of Industrial Medicine, 29, pp. 209-214, (1996)
[6]  
Saroch M., Srivastava S., Fink D., Chandra A., Room temperature ammonia gas sensing using mixed conductor based TEMPOS structures, Sensors, 8, pp. 6355-6370, (2008)
[7]  
Kondawar S.B., Agrawal S.P., Nimkar S.H., Sharma H.J., Patil P.T., Conductive polyaniline tin oxide nanocomposites for ammonia sensor, Advanced Materials Letters, 5, pp. 393-398, (2012)
[8]  
Abel T., Ungerbock B., Klimant I., Mayr T., Fast responsive, optical trace level ammonia sensor for environmental monitoring, Chemistry Central Journal, 6, (2012)
[9]  
Hanson D.R., McMurry P.H., Jiang J., Tanner D., Huey L.G., Ambient pressure proton transfer mass spectrometry: Detection of amines and ammonia, Environmental Science & Technology, 45, pp. 8881-8888, (2011)
[10]  
Mirica K.A., Azzarelli J.M., Weis J.G., Schnorr J.M., Swager T.M., Rapid prototyping of carbon-based chemiresistive gas sensors on paper, Proceedings of the National Academy of Sciences, 110, pp. E3265-E3270, (2013)