Thermodynamic and GMDH Modeling of CO2 and H2S Solubility in Aqueous Sulfolane Solution

被引:0
作者
Morteza Esfandyari
Mahdi Koolivand Salooki
Mohammad Shokouhi
Yusefali Ghorbani
机构
[1] University of Bojnord,Department of Chemical Engineering
[2] Research Institute of Petroleum Industry (RIPI),Catalyst Technologies Development Division
[3] Research Institute of Petroleum Industry (RIPI),undefined
来源
Journal of Solution Chemistry | 2021年 / 50卷
关键词
Thermodynamical modeling; GMDH approach; Mixed solvent; Aqueous sulfolane solution; Hydrogen sulfide; Carbon dioxide;
D O I
暂无
中图分类号
学科分类号
摘要
The solubility of hydrogen sulfide (H2S) and carbon dioxide (CO2) in mixed solvents were modeled using two approaches. The Gibbs excess energy of mixed solvents such as modified Pitzer as thermodynamic approach and GMDH as an artificial intelligence approaches which both have been adopted to analyze the reported experimental data in literature. The precision of the modified Pitzer and GMDH models are compared with each other and also with experimental data. The obtained results show that the modified Pitzer and GMDH have acceptable agreement with experimental reported data and also GMDH could be an acceptable alternative model for the modified Pitzer one.
引用
收藏
页码:1 / 18
页数:17
相关论文
共 103 条
[1]  
Shokouhi M(2019)Carbon dioxide solubility in aqueous sulfolane solution J. Chem. Thermodyn. 132 62-72
[2]  
Jalili AH(2010)Acid gases partial pressures above a 50 wt% aqueous methyldiethanolamine solution: Experimental work and modeling Fluid Phase Equilib. 289 99-109
[3]  
Zoghi AT(2015)Measuring the solubility of CO J. Che. Thermodyn. 85 13-25
[4]  
Ahari JS(1990) and H Fluid Phase Equilib. 56 313-324
[5]  
Dicko M(2015)S in sulfolane and the density and viscosity of saturated liquid binary mixtures of (sulfolane + CO Int. J. Greenhouse Gas Control 42 87-97
[6]  
Coquelet C(1988)) and (sulfolane+ H Can. J. Chem. Eng. 66 519-520
[7]  
Jarne C(2011)S) Fluid Phase Equilib. 306 190-203
[8]  
Northrop S(2019)Solubility of H J. Chem. Thermodyn. 135 133-142
[9]  
Richon D(2018)S, CO Chem. Phys. Lett. 707 22-30
[10]  
Jalili AH(1995), CH Int. J. Production Res. 33 1229-1240