Separation of europium from aqueous solutions using Al3+- and Fe3+-doped zirconium and titanium phosphates

被引:0
作者
P. Misaelides
P. Misaelides
P. Misaelides
S. Sarri
S. Sarri
S. Sarri
D. Zamboulis
D. Zamboulis
D. Zamboulis
G. Gallios
G. Gallios
G. Gallios
I. Zhuravlev
V. V. Strelko
机构
[1] Department of Chemistry,
[2] Aristotle University,undefined
[3] Department of Chemistry,undefined
[4] Aristotle University,undefined
[5] Department of Chemistry,undefined
[6] Aristotle University,undefined
[7] Department of Chemistry,undefined
[8] Aristotle University,undefined
[9] Department of Chemistry,undefined
[10] Aristotle University,undefined
[11] Department of Chemistry,undefined
[12] Aristotle University,undefined
[13] Department of Chemistry,undefined
[14] Aristotle University,undefined
[15] Department of Chemistry,undefined
[16] Aristotle University,undefined
[17] Department of Chemistry,undefined
[18] Aristotle University,undefined
[19] Department of Chemistry,undefined
[20] Aristotle University,undefined
[21] Department of Chemistry,undefined
[22] Aristotle University,undefined
[23] Department of Chemistry,undefined
[24] Aristotle University,undefined
[25] Institute of Sorption and Endoecology Problems,undefined
[26] National Academy of Science of Ukraine,undefined
[27] Institute of Sorption and Endoecology Problems,undefined
[28] National Academy of Science of Ukraine,undefined
来源
Journal of Radioanalytical and Nuclear Chemistry | 2006年 / 268卷
关键词
Phosphate; Titanium; Physical Chemistry; Aqueous Solution; Zirconium;
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摘要
The sorption of europium from aqueous solutions (Eu-concentration: 10 to 250 mg/l) by Fe3+- and Al3+-doped zirconium- and titanium-phosphates was investigated using a batch technique and 152Eu tracer. The initial pH of the solutions was adjusted to 3, 4, 5 and 6. All investigations were performed under constant ionic strength, I=0.15 established by NaCl.<span lang=EN-GB style='font-size:12.0pt;mso-ansi-language:EN-GB'>Although zirconium phosphates generally showed a higher Eu-uptake capacity than the titanium ones, all investigated materials possessed the ability to remove considerable amounts of europium from aqueous solutions. The Eu-sorption properties of the studied phosphate materials<span style='font-size:12.0pt'>seem to be not especially affected by the type of trivalent cations used for the doping (i.e., Al3+or Fe3+).
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页码:53 / 58
页数:5
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