First example of ruthenium nitroso monoammine complex. Crystal structure of [Ru(NO)(NH3)3(H2O)Cl] × [Ru(no)(NH3)3(OH)Cl][Ru(NO)(NH3)Cl4]2Cl·2H2O

被引：0
作者：
M. A. Il’in
V. A. Emel’yanov
I. A. Baidina
机构：
[1] Russian Academy of Sciences,A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division
[2] Novosibirsk State University,undefined
来源：
Journal of Structural Chemistry | 2010年 / 51卷
关键词：
ruthenium; nitroso complexes; ammine complexes; chloro complexes; single crystal X-ray diffraction analysis; IR spectroscopy;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The structure of the interaction products of (NH4)2[Ru(NO)Cl5] solution with ammonium acetate on heating is studied. The crystal structure of the [Ru(NO)(NH3)3(H2O)Cl][Ru(NO)(NH3)3(OH)Cl] × [Ru(NO)(NH3)Cl4]2Cl-2H2O compound (compound I) containing a previously unknown anion of the nitrosomonoammine series is determined: Cc space group; a = 33.530(7) Å, b = 8.202(2) Å, c = 11.844(2) Å; β= 101.54(3)°.
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页码：99 / 106
页数：7
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