First example of ruthenium nitroso monoammine complex. Crystal structure of [Ru(NO)(NH3)3(H2O)Cl] × [Ru(no)(NH3)3(OH)Cl][Ru(NO)(NH3)Cl4]2Cl·2H2O

被引：0
作者：
M. A. Il’in
V. A. Emel’yanov
I. A. Baidina
机构：
[1] Russian Academy of Sciences,A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division
[2] Novosibirsk State University,undefined
来源：
Journal of Structural Chemistry | 2010年 / 51卷
关键词：
ruthenium; nitroso complexes; ammine complexes; chloro complexes; single crystal X-ray diffraction analysis; IR spectroscopy;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The structure of the interaction products of (NH4)2[Ru(NO)Cl5] solution with ammonium acetate on heating is studied. The crystal structure of the [Ru(NO)(NH3)3(H2O)Cl][Ru(NO)(NH3)3(OH)Cl] × [Ru(NO)(NH3)Cl4]2Cl-2H2O compound (compound I) containing a previously unknown anion of the nitrosomonoammine series is determined: Cc space group; a = 33.530(7) Å, b = 8.202(2) Å, c = 11.844(2) Å; β= 101.54(3)°.
引用
收藏
页码：99 / 106
页数：7
相关论文
共 50 条
  • [1] FIRST EXAMPLE OF RUTHENIUM NITROSO MONOAMMINE COMPLEX. CRYSTAL STRUCTURE OF [Ru(NO)(NH3)3(H2O)Cl] x [Ru(NO)(NH3)3(OH)Cl][Ru(NO)(NH3)Cl4]2Cl•2H2O
    Il'in, M. A.
    Emel'yanov, V. A.
    Baidina, I. A.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2010, 51 (01) : 99 - 106
  • [2] Structure and synthesis of nitrosoruthenium trans-diammines [Ru(NO)(NH3)2Cl3] and [Ru(NO)(NH3)2(H2O)Cl2]Cl•H2O
    Il'in, M. A.
    Emel'yanov, V. A.
    Baidina, I. A.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2008, 49 (06) : 1090 - 1097
  • [3] Structure and synthesis of nitrosoruthenium trans-diammines [Ru(NO)(NH3)2Cl3] and [Ru(NO)(NH3)2(H2O)Cl2]Cl·H2O
    M. A. Il’in
    V. A. Emel’yanov
    I. A. Baidina
    Journal of Structural Chemistry, 2008, 49 : 1090 - 1097
  • [4] STRUCTURE OF THE FIRST NITROSOAMMINE COMPLEXES OF RUTHENIUM WITH A COORDINATED SULFATE ION: [Ru(NO)(NH3)4(SO4)](HSO4)•H2O AND [Ru(NO)(NH3)3Cl(SO4)]•2H2O
    Makhinya, A. N.
    Shusharina, E. A.
    Baidina, I. A.
    Il'in, M. A.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2011, 52 (05) : 946 - 953
  • [5] Synthesis and crystal structure of trans-[Ru(NO)(NH3)4SO4]ClO4 and [Ru(NO)(NH3)4SO4][Ru(NO)(NH3)3Cl(SO4)]HSO4•H2O
    A. N. Makhinya
    M. A. Il’in
    I. A. Baidina
    I. V. Korol’kov
    Journal of Structural Chemistry, 2016, 57 : 1182 - 1187
  • [6] Structure of the first nitrosoammine complexes of ruthenium with a coordinated sulfate ion: [Ru(NO)(NH3)4(SO 4)](HSO4)·H2O and [Ru(NO)(NH 3)3Cl(SO4)]·2H2O
    Makhinya A.N.
    Shusharina E.A.
    Baidina I.A.
    Il'in M.A.
    Journal of Structural Chemistry, 2011, 52 (5) : 946 - 953
  • [7] [Ru(NH3) 6](MoO4) Cl•3H2O AND [M(NH3)6](ReO4)3•2H2O (M = Ru, Ir). SYNTHESIS AND CRYSTAL STRUCTURE
    Khranenko, S. P.
    Bykova, E. A.
    Yusenko, K. V.
    Tyutyunnik, A. P.
    Gromilov, S. A.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2013, 54 (05) : 931 - 936
  • [8] [Ru(NH3)6](MoO4)Cl·3H2O and [M(NH3)6](ReO4)3·2H2O (M = Ru, Ir). Synthesis and crystal structure
    S. P. Khranenko
    E. A. Bykova
    K. V. Yusenko
    A. P. Tyutyunnik
    S. A. Gromilov
    Journal of Structural Chemistry, 2013, 54 : 931 - 936
  • [9] Synthesis and crystal structure of trans-[Ru(NO)(NH3)4SO4]ClO4 and [Ru(NO)(NH3)4SO4][Ru(NO)(NH3)3Cl(SO4)]HSO4aEuro¢H2O
    Makhinya, A. N.
    Il'in, M. A.
    Baidina, I. A.
    Korol'kov, I. V.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2016, 57 (06) : 1182 - 1187
  • [10] Cellular effects of transferrin coordinated to [Cl(NH3)5Ru]Cl2 and cis-[Cl2(NH3)4Ru]Cl
    Frasca, DR
    Gehrig, LE
    Clarke, MJ
    JOURNAL OF INORGANIC BIOCHEMISTRY, 2001, 83 (2-3) : 139 - 149
12345