Simple model for attraction between like-charged polyions

被引:0
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作者
J.J. Arenzon
J.F. Stilck
Y. Levin
机构
[1] Instituto de Física,
[2] Universidade Federal do Rio Grande do Sul Caixa Postal 15051,undefined
[3] Instituto de Física,undefined
[4] Universidade Federal Fluminense Av. Litorânea,undefined
[5] Instituto de Física,undefined
[6] Universidade Federal do Rio Grande do Sul Caixa Postal 15051,undefined
关键词
PACS. 61.20.Qg Structure of associated liquids: electrolytes, molten salts, etc. - 61.25.Hq Macromolecular and polymer solutions; polymer melts; swelling;
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摘要
We present a simple model for the possible mechanism of appearance of attraction between like charged polyions inside a polyelectrolyte solution. The attraction is found to be short ranged, and exists only in the presence of multivalent counterions. It is produced by the correlations in layers of condensed counterions surrounding each polyion and is only weakly temperature dependent. We find the attraction to be maximum at zero temperature and dimish as the temperature is raised. The attraction is only possible if the number of condensed counterions exceeds the threshold, \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$n > Z/2\alpha $$ \end{document}, where α is the valence of counterions and Z is the polyion charge.
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页码:79 / 82
页数:3
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