A screening study on the activation energy of vanadate‐based catalysts for diesel soot combustion

被引：3
作者：
Claudio Badini
Guido Saracco
Nunzio Russo
Vito Specchia
机构：
来源：
Catalysis Letters | 2000年 / 69卷
关键词：
Cs–K–V catalysts; diesel soot; catalytic combustion; activation energy; catalyst stability;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The activation energy of carbon combustion catalysed by alkali vanadates or alkali vanadates/chlorides mixtures is assessed by the Ozawa method. The most active catalyst, Cs4V2O7, entails more than 50% decrease of the activation energy compared to non‐catalytic combustion (from 157 down to 75 kJ/mol). The catalyst performance is enhanced when the catalyst is dissolved in a eutectic liquid (e.g., AgCl + CsCl), which likely improves the catalyst/carbon contact conditions.
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页码：207 / 215
页数：8
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