A New Tubular Borate Built By [B14O24(OH)6]12− Cluster Units

被引：0
作者：
Xiao-Shuang Sun
Dan Qin
Xu-Yan Li
Guo-Yu Yang
机构：
[1] Beijing Institute of Technology,Key Laboratory of Cluster Science, Ministry of Education, School of Chemistry and Chemical Engineering
来源：
Chemical Research in Chinese Universities | 2022年 / 38卷
关键词：
Alkali and alkaline-earth metal; Borate; Tube; Solvothermal synthesis; Cluster;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A new mixed alkali and alkaline-earth metal borate Na4Ca2[B14O22(OH)6]·2H2O(1) has been made under a mild solvothermal condition and characterized by single-crystal X-ray diffraction, infrared(IR) spectroscopy, UV-Vis diffuse reflectance spectroscopy, powder X-ray diffraction and thermogravimetric analysis, respectively. Compound 1 features a 1D tube based on [B14O24(OH)6]12−({B14}-1) oxo-boron clusters. Such a tube built by {B14}-1 units has been discovered for the first time in borate system. These tubes are arranged orderly to generate 2D layers and a further 3D supramolecular network through hydrogen bond interactions. UV-Vis diffuse reflectance spectrum reveals that compound 1 is a wide band-gap semiconductor and has potential application in UV region.
引用
收藏
页码：123 / 127
页数：4
相关论文
共 164 条
[31]  
Zhou W W(1986)undefined Top. Curr. Chem. 131 39-undefined
[32]  
Wu K J(1977)undefined Phys. Chem. Miner. 2 59-undefined
[33]  
Huang J S(2006)undefined Inorg. Chem. 45 1430-undefined
[34]  
Wu H P(2013)undefined Inorg. Chem. 52 10566-undefined
[35]  
Pan S L(2019)undefined Chem. Commun. 55 1295-undefined
[36]  
Kenneth R P(2014)undefined J. Clust. Sci. 25 617-undefined
[37]  
Li H Y(2016)undefined Dalton Trans. 45 13937-undefined
[38]  
Jia D Z(2019)undefined J. Clust. Sci. 30 1139-undefined
[39]  
Chen Z H(1966)undefined J. Res. Natl. Bur. Stand. 70A 153-undefined
[40]  
Fan X Y(undefined)undefined undefined undefined undefined-undefined
12345678910