Synthesis of FeCoMnAPO-5 Molecular Sieve and Catalytic Activity in Cyclohexane Oxidation by Oxygen

被引:14
作者
Lipeng Zhou
Jie Xu
Hong Miao
Xiaoqiang Li
Feng Wang
机构
[1] Chinese Academy of Sciences,State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Graduate School of the
来源
Catalysis Letters | 2005年 / 99卷
关键词
molecular sieves; aluminophosphate; oxidation; cyclohexane;
D O I
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中图分类号
学科分类号
摘要
A new FeCoMnAPO-5 with AFI structure was synthesized under hydrothermal conditions and characterized by XRD, FT-IR, X-ray fluorescence, nitrogen adsorption and SEM. The oxidation of cyclohexane with molecular oxygen was studied over the catalyst at 403 K. It show d higher activity compared to FeAPO-5, CoAPO-5 and MnAPO-5. The FeCoMnAPO-5 catalyst was recycled twice without loss of activity or selectivity.
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页码:231 / 234
页数:3
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共 36 条
  • [1] Hartmanm M.(1999)undefined Chem. Rev. 99 635-undefined
  • [2] Kevan L.(1999)undefined J. Am. Chem. Soc. 121 11926-undefined
  • [3] Raja R.(1998)undefined Catal. Lett. 55 15-undefined
  • [4] Sankar G.(1995)undefined Angew Chem. Int. Ed. Engl 34 560-undefined
  • [5] Thomas J.M.(1994)undefined Appl. Catal. A 118 51-undefined
  • [6] Sankar G.(2001)undefined Catal. Lett. 75 159-undefined
  • [7] Raja R.(1996)undefined J. Phys. Chem 100 8977-undefined
  • [8] Thomas J.M.(1989)undefined Zeolites 9 474-undefined
  • [9] Vanoppen DL(1996)undefined J. Chem. Soc., Faraday Trans. 92 1257-undefined
  • [10] De Vos DE(1996)undefined Mircopor. Mater. 6 1-undefined