A review on the removal of phthalate acid esters in wastewater treatment plants: from the conventional wastewater treatment to combined processes

In the past decades, phthalate acid esters (PAEs), as a new class of recalcitrant environmental contaminant, have attracted increasing concern due to their potential hazards to reproductive system. wastewater treatment plants (WWTPs) are generally regarded as a crucial barrier to prevent a variety of contaminants from introducing into aquatic environment. This paper reviews the occurrence, fate, and removal efficacy of six widely appearing PAEs in conventional wastewater treatment. PAEs removal appears to be compound- and process-dependent. Advanced treatment processes, including activated carbon, advanced oxidation process (AOPs), membrane filtration, and membrane bioreactor, show good performance in PAEs elimination, but many methods have been commercially limited by toxic byproducts, high operation, and maintenance costs. Even though combined processes are qualified as a promising alternative, further studies are required to optimize these processes, especially the competitiveness between technique and economy.