Diffusion in garnet: a review

被引:31
作者
Li B. [1 ,2 ]
Ge J. [1 ,2 ]
Zhang B. [1 ]
机构
[1] Key Laboratory for High-Temperature and High-Pressure Study of the Earth’s Interior, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang
[2] University of Chinese Academy of Sciences, Beijing
关键词
Diffusion; Garnet; High temperature and high pressure; Point defects;
D O I
10.1007/s11631-017-0187-x
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
With improvements on high-pressure experimental techniques in multi-anvil apparatus and the development of new analytical tools, major progress has been made on diffusion in garnets in the past several decades. The data obtained in the experimental determination of diffusion coefficients in garnets are of fundamental importance for diffusion modeling and timescales of geological and planetary processes. In this review, we have compiled experimental data on self-diffusion (Si, O, cations), trace element diffusion (Li, Y, Ga, Cr, Sr, REEs), and interdiffusion (Ca–Fe/Mg, Si–Al) in garnet in the light of new advances and recent applications. In addition, some empirical relationships among diffusion parameters (pre-exponential factor D0, activation energy E, ionic radius) are also discussed. We hope that this review can provide a useful data digest and guide to future study of diffusion in garnet. © 2017, The Author(s).
引用
收藏
页码:19 / 31
页数:12
相关论文
共 82 条
[1]  
Bejina F., Jaoul O., Silicon diffusion in silicate minerals, Earth Planet Sci Lett, 153, pp. 229-238, (1997)
[2]  
Bejina F., Jaoul O., Liebermann R.C., Diffusion in minerals at high pressure: a review, Phys Earth Planet Inter, 139, pp. 3-20, (2003)
[3]  
Borinski S.A., Hoppe U., Chakraborty S., Ganguly J., Bhowmik S.K., Multicomponent diffusion in garnets I: general theoretical considerations and experimental data for Fe–Mg systems, Contrib Mineral Petrol, 164, pp. 571-586, (2012)
[4]  
Brady J.B., Diffusion data for silicate minerals, glasses, and liquids, Mineral physics & crystallography: a handbook of physical constants, pp. 269-290, (1995)
[5]  
Brady J.B., Cherniak D.J., Diffusion in minerals: an overview of published experimental data, Rev Mineral Geochem, 72, pp. 899-920, (2010)
[6]  
Cahalan R.C., Kelly E.D., CaRlso W.D., Rates of Li diffusion in garnet: coupled transport of Li and Y + REEs, Am Mineral, 99, 8-9, pp. 1676-1682, (2014)
[7]  
Carlson W.D., Rates of Fe, Mg, Mn and Ca diffusion in garnet, Am Mineral, 91, pp. 1-11, (2006)
[8]  
Carlson W.D., Rates and mechanism of Y, REE, and Cr diffusion in garnet, Am Mineral, 97, pp. 1598-1618, (2012)
[9]  
Carlson W.D., Gale J.G., Wright K., Incorporation of Y and REEs in aluminosilicate garnet: energetics from atomistic simulation, Am Mineral, 99, pp. 1022-1034, (2014)
[10]  
Chakraborty S., Rates and mechanisms of Fe–Mg interdiffusion in olivine at 980–1300 C, J Geophys Res, 102, B6, pp. 12317-12331, (1997)