Preparation of Silicon Thin Films of Different Phase Composition from Monochlorosilane as a Precursor by RF Capacitive Plasma Discharge

被引:0
作者
L. A. Mochalov
R. A. Kornev
A. V. Nezhdanov
A. I. Mashin
A. S. Lobanov
A. V. Kostrov
V. M. Vorotyntsev
A. V. Vorotyntsev
机构
[1] Institute of Applied Physics of the Russian Academy of Sciences,
[2] Lobachevsky State University of Nizhny Novgorod,undefined
[3] Nizhny Novgorod State Technical University n.a. R.E. Alekseev,undefined
来源
Plasma Chemistry and Plasma Processing | 2016年 / 36卷
关键词
PECVD; Monochlorosilane; Raman spectroscopy; Silicon thin films; IR-spectroscopy;
D O I
暂无
中图分类号
学科分类号
摘要
Monochlorosilane/argon/hydrogen (SiH3Cl-Ar-H2) mixture of different ratios was investigated from the point of PECVD application. RF capacitive plasma discharge of 40.68 MHz frequency was used. The process of deposition was studied by optical emission spectroscopy. The silicon thin films of different phase composition were obtained. The thin films were characterized by Raman-spectroscopy, atomic force microscopy, and secondary ion mass spectrometry. The exhaust gas mixture was analyzed by IR-spectroscopy in outlet of the reactor during PECVD process. The chemical mechanism for the deposition process was also proposed.
引用
收藏
页码:849 / 856
页数:7
相关论文
共 38 条
  • [1] Mansfeld DA(2014)Deposition of microcrystalline silicon in ECR discharge (24 GHz) plasma from silicon tetrafluotide precursor Thin Solid Films 562 114-117
  • [2] Vodopyanov AV(2014)Study of silicon tetrafluoride reduction with hydrogen in RF discharge High Energy Chem 48 49-53
  • [3] Golubev SV(1986)Mechanism of silicon film deposition in the RF plasma reduction of silicon tetrachloride Plasma Chem Plasma Process 6 109-125
  • [4] Sennikov PG(1994)Fast growth of hydrogenated amorphous silicon from dichlorsilane Appl Phys Lett 65 1940-1942
  • [5] Mochalov LA(1998)Intrinsic microcrystalline silicon by plasma enhanced chemical vapor deposition from dichlorsilane Appl Phys Lett 73 1236-1238
  • [6] Andreev BA(2008)High density microwave plasma-enhanced chemical vapor deposition of microcrystalline silicon from dichlorsilane Thin Solid Films 516 6585-6591
  • [7] Drozdov Yu N(2010)Fast deposition of microcrystalline Si films from SiH Sol Energy Mater 94 524-526
  • [8] Drozdov MN(1996)Cl Appl Phys Lett 69 1131-1133
  • [9] Shashkin VI(2001) using a high-density microwave plasma source for Si thin film solar sell J Phys Chem 105 2015-2022
  • [10] Bulkin P(undefined)Preparation of wide band gap microcrystalline silicon film by using SiH undefined undefined undefined-undefined