Synthesis of nickel oxide nanorods by Aloe vera leaf extract: Study of its electrochemical properties and catalytic effect on the thermal decomposition of ammonium perchlorate

被引：0

作者：

Modanlou Juibari N. ^{[1
]}

Eslami A. ^{[1
]}

机构：

[1] Department of Inorganic Chemistry, Faculty of Chemistry, University of Mazandaran, Babolsar

来源：

Journal of Thermal Analysis and Calorimetry | 2019年 / 136卷 / 02期

关键词：

Electrochemical property; Green synthesis; Nanorods; Supercapacitor; Thermal decomposition;

D O I：

10.1007/s10973-018-7640-x

中图分类号：

学科分类号：

摘要：

Nickel oxide nanorods were synthesized simply using Aloe vera extract solution and characterized by Fourier transform infrared spectroscopy and powder X-ray diffraction and the morphology of synthesized NiO nanorods were investigated by using of scanning electron microscopy technique. The electrochemical feature and specific capacitance of NiO nanorods were investigated by cyclic voltammetry method, and the results showed the high specific capacitance of NiO nanorods (about 1965 Fg−1). Also, the catalytic activity of NiO nanorods on the thermal decomposition of ammonium perchlorate (AP) was studied by differential scanning calorimetry and thermogravimetry analysis. The results indicated that addition of NiO nanorods increased the heat of decomposition of AP from 450 Jg−1 to 1450 Jg−1 and decreased the temperature of high-temperature decomposition step from 420 °C to about 351 °C. Also, the rate constant (k) enhanced from 5.7(± 0.2) × 10−3 to 1.4(± 0.2) × 10−2 s−1 in the presence of NiO nanorods via catalytic path. © 2018, Akadémiai Kiadó, Budapest, Hungary.

引用

页码：913 / 923

页数：10

共 67 条

[1]

Kharissova O.V., Dias H., Kharisov B.I., Perez B.O., Perez V.M.J., The greener synthesis of nanoparticles, Trends Biotechnol, 31, pp. 240-248, (2013)

[2]

Raveendran P., Fu J., Wallen S.L., Completely green synthesis and stabilization of metal nanoparticles, J Am Chem Soc, 125, pp. 13940-13941, (2003)

[3]

Sharma H.S., Ali S.F., Hussain S.M., Schlager J.J., Sharma A., Influence of engineered nanoparticles from metals on the blood–brain barrier permeability, cerebral blood flow, brain edema and neurotoxicity. An experimental study in the rat and mice using biochemical and morphological approaches, J Nanosci Nanotechnol, 9, pp. 5055-5072, (2009)

[4]

Narayanan S., Sathy B.N., Mony U., Koyakutty M., Nair S.V., Menon D., Biocompatible magnetite/gold nanohybrid contrast agents via green chemistry for MRI and CT bioimaging, ACS Appl Mater Interfaces, 4, pp. 251-260, (2012)

[5]

Njagi E.C., Huang H., Stafford L., Genuino H., Galindo H.M., Collins J.B., Hoag G.E., Suib S.L., Biosynthesis of iron and silver nanoparticles at room temperature using aqueous sorghum bran extracts, Langmuir, 27, pp. 264-271, (2011)

[6]

Govindaraju K., Basha S.K., Kumar V.G., Singaravelu G., Silver, gold and bimetallic nanoparticles production using single cell protein (Spirulina platensis), J Mater Sci, 43, pp. 5115-5122, (2008)

[7]

Shankar S.S., Rai A., Ahmad A., Sastry M., Rapid synthesis of Au, Ag, and bimetallic Au core–Ag shell nanoparticles using Neem (Azadirachta indica) leaf, Broth J Colloid Interface Sci, 27, pp. 5496-5502, (2004)

[8]

Ahmad N., Sharma S., Alam M.K., Singh V.N., Shamsi S.F., Mehta B.R., Fatma A., Rapid synthesis of silver nanoparticles using dried medicinal plant of basil, Colloids Surf B Biointerfaces, 81, pp. 81-86, (2010)

[9]

Kasthuri J., Veerapandian S., Rajendiran N., Biological synthesis of silver and gold nanoparticles using apiin as reducing agent, Colloids Surf B Biointerfaces, 68, pp. 55-60, (2009)

[10]

Panigrahi S., Kundu S., Ghosh S., Nath S., Pal T., General method of synthesis for metal nanoparticles, J Nanoparticle Res, 6, pp. 411-416, (2004)

← 1 2 3 4 5 6 7 →