A different method for producing a flexible LiMn2O4/MWCNT composite electrode for lithium ion batteries

被引:0
作者
Tugrul Cetinkaya
Ahsen Akbulut
Mehmet O. Guler
Hatem Akbulut
机构
[1] Sakarya University,Department of Metallurgical & Materials Engineering, Engineering Faculty
[2] Sakarya University,Department of Environmental Engineering, Engineering Faculty
来源
Journal of Applied Electrochemistry | 2014年 / 44卷
关键词
LiMn; O; /MWCNT; Flexible electrode; Composites; Electrochemical performance;
D O I
暂无
中图分类号
学科分类号
摘要
A flexible lithium manganese oxide (LiMn2O4)/multi-wall carbon nanotube (MWCNT) composite electrode was produced by casting a slurry-containing powdered LiMn2O4 on a previously prepared MWCNT paper. The structure of this new LiMn2O4/MWCNT composite electrode was characterized using scanning electron microscopy and X-ray diffraction patterns. Furthermore, the surfaces of these electrodes were coated with gold–palladium alloy using an RF magnetron sputtering technique to prevent Mn dissolution. To investigate the electrochemical performance of this flexible LiMn2O4/MWCNT composite electrode, a bare-LiMn2O4 electrode was prepared. The discharge capacity of the produced LiMn2O4/MWCNT nanocomposite electrode was cyclically tested, and the charge transfer resistance of the electrodes was studied using electrochemical impedance spectroscopy. Consequently, the Au–Pd-coated LiMn2O4/MWCNT had a 120 mAh g−1 discharge capacity and 90 % capacity retention after 100 cycles.
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页码:209 / 214
页数:5
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[1]  
Chew SY(2009)undefined Carbon 47 2976-2983
[2]  
Ng SH(2010)undefined Electrochem Commun 12 1467-1470
[3]  
Wang J(2008)undefined Electrochem Commun 10 1724-1727
[4]  
Novak P(2011)undefined Chem Commun 47 9669-9671
[5]  
Krumeich P(2008)undefined Mater Res Bull 43 2285-2294
[6]  
Chou SL(2006)undefined J Colloid Inteface Sci 300 633-639
[7]  
Chen J(2006)undefined Mater Lett 60 3251-3254
[8]  
Liu HK(2004)undefined Electrochim Acta 49 1623-1628
[9]  
Wang JZ(2007)undefined Mater Chem Phys 101 276-279
[10]  
Zhong C(2008)undefined Mater Res Bull 43 2119-2129