Solvent effect on the kinetics of carbamoylation of alcohols

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作者
R. G. Makitra
G. G. Midyana
E. Ya. Pal’chikova
A. V. Romanyuk
机构
[1] National Academy of Sciences of Ukraine,Department of Physical Chemistry of Fossil Fuels, Litvinenko Institute of Physical Organic and Coal Chemistry
[2] National Academy of Sciences of Ukraine,Institute of Geology and Geochemistry of Fossil Fuels
[3] “L’vovskaya politekhnika” National University,undefined
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关键词
Isocyanate; Nitrobenzene; Reactant Ratio; Butyl Acetate; BuOH;
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摘要
Solvent effect on the rate of the reaction of phenyl isocyanate with alcohols may be described by multiparameter linear equations. Correlation analysis of the effects of various factors showed that specific solvation inhibits the reaction and that increased solvent polarity favors the process.
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页码:25 / 31
页数:6
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