Change of the scaling behavior of the end-to-end square distance in a two-dimensional polydisperse system

被引:0
作者
Y. Rouault
机构
[1] Max-Planck-Institut für Polymerforschung,
[2] Ackermannweg 10,undefined
[3] 55128 Mainz,undefined
[4] Germany,undefined
来源
The European Physical Journal B - Condensed Matter and Complex Systems | 1998年 / 4卷
关键词
PACS. 61.25.Hq Macromolecular and polymer solutions; polymer melts; swelling - 05.50.+q Lattice theory and statistics; Ising problems - 64.60.Cn Order-disorder transformations; statistical mechanics of model systems;
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摘要
The simulation of a two-dimensional, broadly polydisperse, living polymers system at high concentration reveals an unusual conformational behaviour for the longer chains. Unlike in three dimensions, the longer chains are not swollen but are squeezed by the smaller chains. This observation is discussed in terms of a two dimensional solvent- polymer mixture whose solvent particules are larger than the polymer monomers.
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页码:61 / 64
页数:3
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