Influence of various series of additives on the clouding behavior of aqueous solutions of triblock copolymers

被引:0
|
作者
Arifa Shaheen
Navjot Kaur
Rakesh Kumar Mahajan
机构
[1] Guru Nanak Dev University,Department of Chemistry
来源
Colloid and Polymer Science | 2008年 / 286卷
关键词
Cloud point; Hydrotropes; Triblock copolymers; Ionic surfactants;
D O I
暂无
中图分类号
学科分类号
摘要
The cloud point (CP) studies on aqueous solutions of two ethylene oxide-propylene oxide triblock copolymers (EO)2.5(PO)31(EO)2.5 and (EO)13(PO)30(EO)13 with varying number of ethylene oxide (EO) units were carried out in the presence of series of additives, such as alkali, acids, ionic surfactants, alcohols, salts, and hydrotropes. The results of this study show that sodium hydroxide decreases the CP of the two copolymers. Acids increase the CP in the order hydrochloric acid > acetic acid > formic acid for both the triblock copolymers. Hydrotropes increase the CP, whereas salts decrease or increase the CP based on their salting-out/salting-in nature. Alcohols, which are polar organic additives, affect the CP of the two copolymers differently. The change in the CP of the triblock copolymers depends upon the structure and concentration of the additives and on the number of EO units of the two triblock copolymers.
引用
收藏
页码:319 / 325
页数:6
相关论文
共 21 条
  • [21] Poly(N-vinylcaprolactam)-b-poly(ethylene glycol)-b-poly (N-vinylcaprolactam) Triblock Copolymers Synthesis by ATRP and thermal gelation properties of the aqueous solutions
    Negru, Ioana
    Teodorescu, Mircea
    Stanescu, Paul O.
    Draghici, Constantin
    Lungu, Anamaria
    Sarbu, Andrei
    MATERIALE PLASTICE, 2010, 47 (01) : 35 - 41