Complex formation of magnesium and calcium ions with trimethylenediamine-N,N,N’,N’-tetraacetic acid

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作者
S. N. Gridchin
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[1] Ivanovo State University of Chemistry and Technology,
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complexon; stability constant; enthalpy; entropy; ionic strength; magnesium; calcium;
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摘要
Stability constants and heat effects of the formation reactions of magnesium and calcium trimethylenediaminetetraacetates at 298.15 K and ionic strength of 0.1, 0.5, and 1.0 (mol/L KNO3) have been determined by means of potentiometry and calorimetry. Standard thermodynamic parameters (log K0, ΔrG0, ΔrH0, and ΔrS0) of the studied equilibriums have been determined.
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页码:1069 / 1072
页数:3
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