Local structure of Eu3+ ions in fluorophosphate laser glass

被引:1
作者
P. Babu
R. Vijaya
Kyoung Hyuk Jang
Hyo Jin Seo
V. Lavin
C. K. Jayasankar
机构
[1] Pukyong National University,Department of Physics
[2] Govt. Degree and P.G. College,Department of Physics
[3] Sri Venkateswara University,Department of Physics
[4] Universidad de La Laguna,Departamento de Fisica Fundamental y Experimental Electronica y Sistemas
关键词
Site-selective excitation; local structure; Eu; fluorophosphate glass;
D O I
10.1007/s12043-010-0155-z
中图分类号
学科分类号
摘要
A fluorophosphate laser glass doped with 1.0 mol% of Eu3+ ions has been prepared and studied by site-selective spectroscopy to explore the local structure of Eu3+ ions. Site-selective 5D0 → 7F1,2 emission spectra have been measured under resonant excitation to the 5D0 level at different wavelengths within the 7F0 → 5D0 band at 16 K. Using the Stark level positions of the 7F1 and 7F2 levels, crystal-field analysis has been carried out. The results suggest the existence of a unique kind of site for all the environments of Eu3+ ions in this glass.
引用
收藏
页码:1005 / 1010
页数:5
相关论文
共 50 条
[1]   Local field dependent fluorescence properties of Eu3+ ions in a fluorometaphosphate laser glass [J].
Babu, P. ;
Jang, Kyoung Hyuk ;
Kim, Eun Sik ;
Vijaya, R. ;
Jayasankar, C. K. ;
Lavin, Victor ;
Seo, Hyo Jin .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2011, 357 (10) :2139-2147
[2]   Structural and optical investigations on Eu3+ doped fluorophosphate glass and nano glass-ceramics [J].
Hadi, Rahimian ;
Yusef, Hatefi ;
Ali, Dehghan Hamedan ;
Pezhman, Shirmardi Seyed ;
Hossein, Mokhtari .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2018, 487 :46-52
[3]   Effect of excitation and doping concentration on the emission color of a fluorophosphate glass doped with Tb3+and Eu3+ [J].
Saad, Nedra ;
Haouari, Mohamed ;
Ibrahim, Mayssa ;
Amamou, Noura .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2024, 623
[4]   Emission of Eu3+ in SiO2-ZnO glass and SiO2-SnO2 glass-ceramic: Correlation between structure and optical properties of Eu3+ ions [J].
Van Tran, T. T. ;
Dung Cao, T. M. ;
Quang Vinh Lam ;
Van Hieu Le .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2017, 459 :57-62
[5]   Local environment of Eu3+ and Tb3+ ions in fluorophosphate glasses of the Ba(PO3)2-MgCaSrBaAl2F14 system [J].
T. V. Bocharova ;
A. N. Vlasova ;
G. O. Karapetyan ;
V. G. Kuryavyi ;
A. M. Mironov ;
N. O. Tagil’tseva .
Glass Physics and Chemistry, 2008, 34
[6]   PHONON SIDE-BAND SPECTRA AND LOCAL-STRUCTURE AROUND EU3+ IONS IN ALUMINOSILICATE GLASSES [J].
TODOROKI, S ;
HIRAO, K ;
SOGA, N .
NIPPON SERAMIKKUSU KYOKAI GAKUJUTSU RONBUNSHI-JOURNAL OF THE CERAMIC SOCIETY OF JAPAN, 1993, 101 (09) :1065-1067
[7]   Local structure of Eu3+ in borosilicate glasses by phonon sideband spectra [J].
Yao, ZD ;
Ding, Y ;
Nanba, T ;
Miura, Y .
MATERIALS SCIENCE RESEARCH INTERNATIONAL, 1998, 4 (04) :239-243
[8]   Eu3+ as a luminescent probe for the local structure of trivalent dopant ions in barium zirconate-based proton conductors [J].
Haro-Gonzalez, P. ;
Karlsson, M. ;
Gaita, S. M. ;
Knee, C. S. ;
Bettinelli, M. .
SOLID STATE IONICS, 2013, 247 :94-97
[9]   Clarifying the effect of local structure of Ce3+ and Eu3+ on photoluminescence of YAG:Ce,Eu nanophosphors [J].
He, Xiaowu ;
Ren, Yanbiao ;
Hu, Caixia ;
Ma, Ben ;
Chen, Hao ;
Huang, Shushan ;
Hao, Hongyue ;
Qi, Tongtong ;
Liu, Xiaofang ;
Yu, Ronghai .
JOURNAL OF ALLOYS AND COMPOUNDS, 2020, 822
[10]   Eu3+ ion distribution in oxyfluoride glass nanocomposites [J].
Antuzevics, Andris ;
Krieke, Guna ;
Pavlovska, Elina ;
Rogulis, Uldis .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2019, 522