Insights Into the Interfacial Degradation of High-Voltage All-Solid-State Lithium Batteries

被引:0
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作者
Jiawen Li
Yuchen Ji
Haoran Song
Shiming Chen
Shouxiang Ding
Bingkai Zhang
Luyi Yang
Yongli Song
Feng Pan
机构
[1] Peking University Shenzhen Graduate School,School of Advanced Material
[2] Guangdong University of Technology,Guangzhou Key Laboratory of Clean Transportation Energy Chemistry, School of Chemical Engineering and Light Industry
来源
Nano-Micro Letters | 2022年 / 14卷
关键词
Solid-state battery; Poly(ethylene oxide); Surface modification; Interface stability; High-voltage cathode;
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学科分类号
摘要
The cycle performance of poly(ethylene oxide) (PEO)-based all-solid-state lithium batteries with LiCoO2 cathode was greatly improved via coating LiCoO2 with high-voltage stable Li3AlF6.At the upper cutoff voltage of 4.2 V, the poor electrochemical performance is mainly originated from the structure collapse of LiCoO2 at the surface instead of the decomposition of PEO.When the voltage reaches 4.5 V or even higher potentials, the intensive electrochemical decomposition of PEO-based solid polymer electrolyte accelerated interfacial degradation.
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