Sol-gel Synthesis of Porous Crystalline TiO2–P2O5 Oxide with Thermal Stability

被引:0
作者
Donglin Li
Haoshen Zhou
Mitsuhiro Hibino
Itaru Honma
机构
[1] National Institute of Advanced Industrial Science and Technology (AIST),Institute of Energy Electronics
来源
Journal of Materials Research | 2003年 / 18卷
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摘要
Porous TiO2–P2O5 oxide was synthesized by the sol-gel method in the presence of tri-block copolymer (EO)20(PO)70(EO)20 (Pluronic123) in queous solution. The TiO2 nanocrystals with anatase structure precipitated in the as-synthesized TiO2–P2O5 materials at 80°C, considerably lower than that for traditional heat treatment in the solid state, which maintained a stable size of 3.6–4 nm upon calcinations below 500°C. It is believed that P2O5 glass phase prevents the coarsening of TiO2 nanocrystals below 500°C. The mixed oxide exhibited a specific surface area of 170–200 m2/g after calcining in the temperature range of 300–500°C.
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页码:2743 / 2746
页数:3
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