Neutron scattering study of combustion-synthesized Ce1−xCuxO2−x

被引：0

作者：

Keka R. Chakraborty

P. S. R. Krishna

M. S. Hegde

机构：

[1] Bhabha Atomic Research Centre,Solid State Physics Division

[2] Indian Institute of Science,Solid State and Structural Chemistry Unit

来源：

Pramana | 2004年 / 63卷

关键词：

Combustion synthesis; neutron diffraction; 81.20.Ka; 61.12.Ld;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Powder neutron diffraction and Hi-Q neutron diffraction data have been recorded and analysed in order to obtain the local and long range order of Cu in Cudoped CeO2 with three doping levels of Cu. Rietveld method and MCGR techniques of data analysis for the two types of data reveal that the Cu ion is in the 2+ oxidation state and has a vacancy in its first coordination shell. These deductions from the data analysis fit well with the mechanism of catalysis we propose.

引用

页码：245 / 249

页数：4