Regeneration of the iron-molybdenum catalyst for partial oxidation of methanol to formaldehyde

被引:0
作者
I. V. Babichev
A. A. Ilyin
R. N. Rumyantsev
A. P. Ilyin
K. V. Kuryleva
机构
[1] Ivanovo State University of Chemical Technology,Research Institute of Thermodynamics and Kinetics of Chemical Processes
[2] Ivanovo State University of Chemical Technology,undefined
来源
Russian Journal of Applied Chemistry | 2015年 / 88卷
关键词
Molybdenum; Methanol Oxidation; Molybdenum Oxide; Molybdenum Trioxide; Molybdenum Catalyst;
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暂无
中图分类号
学科分类号
摘要
Regeneration of a spent iron-molybdenum catalyst for partial oxidation of methanol to formaldehyde was studied. A stage-by-stage dissolution of molybdenum and iron oxides in solutions of ammonia and weak nitric acid, respectively, is suggested. A dependence of the catalyst composition on the pH of the medium and temperature and its effect on the catalyst properties in the reaction of methanol oxidation to formaldehyde was revealed.
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页码:590 / 594
页数:4
相关论文
共 18 条
  • [1] Rumyantsev RN(2012)undefined Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 55 54-57
  • [2] Ilyin AP(1981)undefined React. Kinet. Catal. Lett. 18 101-105
  • [3] Ilyin AA(1976)undefined Kinet. Catal. 17 338-344
  • [4] Zhukov AB(1976)undefined Kinet. Catal. 17 1242-1248
  • [5] Popov BI(2004)undefined Catal. Lett. 98 161-165
  • [6] Skomorokhova NG(2014)undefined Russ. J. Appl. Chem. 87 265-269
  • [7] Popov B I(undefined)undefined undefined undefined undefined-undefined
  • [8] Bibin V N(undefined)undefined undefined undefined undefined-undefined
  • [9] Boreskov G K(undefined)undefined undefined undefined undefined-undefined
  • [10] Abaulina LI(undefined)undefined undefined undefined undefined-undefined