Pseudohexagonal motif of the arrangement of compex anions in the structure of [Ru(NH3)5Cl]2[Re6S8(CN)6]·3H2O

被引：0
|
作者：
K. V. Yusenko
I. A. Baidina
E. A. Shusharina
S. A. Gromilov
机构：
[1] Russian Academy of Sciences,A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division
[2] Novosibirsk State University,undefined
来源：
Journal of Structural Chemistry | 2008年 / 49卷
关键词：
X-ray diffraction analysis; X-ray phase analysis; ruthenium; rhenium; crystal chemistry; chloropentammine;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The [Ru(NH3)5Cl]2[Re6S8(CN)6]·3H2O salt was obtained; its crystal structure was analyzed: a = 10.7713(9) Å, b = 13.9602(11) Å, c = 14.7956(11) Å, α = 91.961(3)°, β = 109.985(3)°, γ = 110.030(3)°, V = 1935.3(3) Å3, space group P1¯, Z = 2, dcalc = 3.441 g/cm3. In the cluster anion, the Re-Re distances lie in the range from 2.594 Å to 2.612 Å. For two crystallographically independent complex cations, Ru-Nav is 2.105 Å, and Ru-Clav 2.329 Å. A pseudohexagonal motif of the structure was found.
引用
收藏
页码：170 / 174
页数：4
相关论文
共 50 条
  • [21] Synthesis, crystal structure, and properties of [Rh(NH3)5Cl][ReBr6]
    K. V. Yusenko
    S. A. Gromilov
    I. A. Baidina
    I. V. Korolkov
    S. V. Korenev
    Journal of Structural Chemistry, 2005, 46 : 109 - 115
  • [22] First example of ruthenium nitroso monoammine complex. Crystal structure of [Ru(NO)(NH3)3(H2O)Cl] × [Ru(no)(NH3)3(OH)Cl][Ru(NO)(NH3)Cl4]2Cl·2H2O
    M. A. Il’in
    V. A. Emel’yanov
    I. A. Baidina
    Journal of Structural Chemistry, 2010, 51 : 99 - 106
  • [23] Synthesis, crystal structure, and properties of [Rh(NH3)5Cl][ReBr6]
    Yusenko, KV
    Gromilov, SA
    Baidina, IA
    Korolkov, IV
    Korenev, SV
    JOURNAL OF STRUCTURAL CHEMISTRY, 2005, 46 (01) : 109 - 115
  • [24] 23-Electron Re6 metal clusters: syntheses and crystal structures of (Ph4P)3[Re6S8(CN)6], (Ph4P)2(H)[Re6Se8(CN)6]·8H2O, and (Et4N)2(H)[Re6Te8(CN)6]·2H2O
    N. G. Naumov
    E. V. Ostanina
    A. V. Virovets
    M. Schmidtman
    A. Müller
    V. E. Fedorov
    Russian Chemical Bulletin, 2002, 51 : 866 - 871
  • [25] 23-Electron Re6 metal clusters:: Syntheses and crystal structures of (Ph4P)3[Re6S8(CN)6], (Ph4P)2(H)[Re6Se8(CN)6] • 8H2O, and (Et4N)2(H)[Re6Te8(CN)6] • 2H2O
    Naumov, NG
    Ostanina, EV
    Virovets, AV
    Schmidtman, M
    Müller, A
    Fedorov, VE
    RUSSIAN CHEMICAL BULLETIN, 2002, 51 (05) : 866 - 871
  • [26] Structure and synthesis of nitrosoruthenium trans-diammines [Ru(NO)(NH3)2Cl3] and [Ru(NO)(NH3)2(H2O)Cl2]Cl•H2O
    Il'in, M. A.
    Emel'yanov, V. A.
    Baidina, I. A.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2008, 49 (06) : 1090 - 1097
  • [27] Structure and synthesis of nitrosoruthenium trans-diammines [Ru(NO)(NH3)2Cl3] and [Ru(NO)(NH3)2(H2O)Cl2]Cl·H2O
    M. A. Il’in
    V. A. Emel’yanov
    I. A. Baidina
    Journal of Structural Chemistry, 2008, 49 : 1090 - 1097
  • [28] Crystal structure of [{Cu(H2O)(en)2}{Cu(en)2}Re6Te8(CN)6]·3H2O
    Yu. V. Mironov
    O. A. Efremova
    V. E. Fedorov
    Journal of Structural Chemistry, 2014, 55 : 360 - 362
  • [29] Crystal structure of [{Cu(H2O)(en)2}{Cu(en)2}Re6Te8(CN)6]•3H2O
    Mironov, Yu. V.
    Efremova, O. A.
    Fedorov, V. E.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2014, 55 (02) : 360 - 362
  • [30] FIRST EXAMPLE OF RUTHENIUM NITROSO MONOAMMINE COMPLEX. CRYSTAL STRUCTURE OF [Ru(NO)(NH3)3(H2O)Cl] x [Ru(NO)(NH3)3(OH)Cl][Ru(NO)(NH3)Cl4]2Cl•2H2O
    Il'in, M. A.
    Emel'yanov, V. A.
    Baidina, I. A.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2010, 51 (01) : 99 - 106
12345