Experimental evaluation of sorptive removal of fluoride from drinking water using iron ore

被引:30
作者
Kebede B. [1 ]
Beyene A. [1 ]
Fufa F. [1 ]
Megersa M. [1 ]
Behm M. [2 ]
机构
[1] Department of Environmental Health Science and Technology, Jimma University, PO Box 378, Jimma
[2] Department of Technology Systems, East Carolina University, 231 Slay Hall, Greenville
关键词
Defluoridation; Fluoride; Iron ore; Water treatment;
D O I
10.1007/s13201-014-0210-x
中图分类号
学科分类号
摘要
High concentrations of fluoride in drinking water is a public health concern globally and of critical importance in the Rift Valley region. As a low-cost water treatment option, the defluoridation capacity of locally available iron ore was investigated. Residence time, pH, agitation rate, particle size of the adsorbent, sorbent dose, initial fluoride concentration and the effect of co-existing anions were assessed. The sorption kinetics was found to follow pseudo-first-order rate and the experimental equilibrium sorption data fitted reasonably well to the Freundlich model. The sorption capacity of iron ore for fluoride was 1.72 mg/g and the equilibrium was attained after 120 min at the optimum pH of 6. The sorption study was also carried out at natural pH conditions using natural ground water samples and the fluoride level was reduced from 14.22 to 1.17 mg/L (below the WHO maximum permissible limit). Overall, we concluded that iron ore can be used in water treatment for fluoride removal in the Rift Valley region and beyond. © 2014, The Author(s).
引用
收藏
页码:57 / 65
页数:8
相关论文
共 31 条
[1]  
Standard methods for examination of water and wastewater. American Public Health Association, American Water Works Association and the Water and Environment Federation, 21th ed, Washington, (2005)
[2]  
Ayoob S., Gupta A.K., Fluoride in drinking water: a review on the status and stress effects, Crit Rev Environ Sci Technol, 36, pp. 433-487, (2006)
[3]  
Ayoob S., Gupta A.K., Venugopal T.B., A conceptual overview on sustainable technologies for the defluoridation of drinking water, Crit Rev Environ Sci Technol, 38, pp. 401-470, (2008)
[4]  
Cengeloglu Y., Kir E., Ersoz M., Removal of fluoride from aqueous solution by using red mud, Sep Purif Technol, 28, pp. 81-86, (2002)
[5]  
Chen S.G., Yang R.T., Theoretical basis for the potential theory adsorption isotherms, the Dubinin–Radushkevich and Dubinin–Astakhov equations, Langmuir, 10, pp. 4244-4249, (1994)
[6]  
Chen N., Zhang Z., Feng C.H., Zhu D., Yang Y., Sugiura N., Preparation and characterization of porous granular ceramic containing dispersed aluminum and iron oxides as adsorbents for fluoride removal from aqueous solution, J Hazard Mater, 186, pp. 863-868, (2011)
[7]  
Edmunds W.M., Smedley P.L., Fluoride in natural waters, Essentials of medical geology, pp. 311-336, (2013)
[8]  
Freundlich H.M.F., Uber die adsorption in losungen, Z Phys Chem, 57A, pp. 385-470, (1906)
[9]  
Gao S., Sun R., Wei Z., Zhao H., Li H., Hu F., Size-dependent defluoridation properties of synthetic hydroxyapatites, J Fluor Chem, 130, pp. 550-556, (2009)
[10]  
Ghorai S., Pant K.K., Equilibrium, kinetics and breakthrough studies for adsorption of fluoride on activated alumina, Sep Purif Technol, 42, pp. 265-271, (2005)