Nonparametric scaled equation of state and approximation of P-ρ-T data near the vapor-liquid critical point

被引:0
作者
P. P. Bezverkhii
V. G. Martynets
É. V. Matizen
机构
[1] Russian Academy of Sciences,Nikolaev Institute of Inorganic Chemistry, Siberian Division
来源
Journal of Experimental and Theoretical Physics | 2004年 / 99卷
关键词
Spectroscopy; State Physics; Field Theory; Comparative Analysis; C2H4;
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摘要
We present a new scaled equation of state adequately describing the P-ρ-T data for fluids near the vapor-liquid transition point and compare this equation to the Schofield parametric equation of state. A comparative analysis of the approximation of data for He4, C2H4, and H2O in the critical region shows that both these equations correctly describe the behavior of thermodynamic functions asymptotically close to the critical point.
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页码:998 / 1004
页数:6
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