Low-temperature emission of singlet oxygen from the surface of transition metal oxides

被引:0
|
作者
O. V. Matrosova
Yu. N. Rufov
M. V. Vishnetskaya
机构
[1] Gubkin Russian State University of Oil and Gas,
[2] Semenov Institute of Chemical Physics,undefined
来源
Russian Journal of Physical Chemistry A | 2010年 / 84卷
关键词
Singlet Oxygen; Maleic Anhydride; Vanadium Oxide; Molybdenum Oxide; Ammonium Metavanadate;
D O I
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中图分类号
学科分类号
摘要
Low-temperature emission of the singlet form of dioxygen 1O2 from the surface of the individual and mixed V and Mo oxides was detected by thermal desorption at 20–350°C. The amount of the desorbing 1O2 and the temperature range of 1O2 emission were found to depend on the composition of the catalyst; the low-temperature 1O2 form can be regenerated after its contact with oxygen.
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页码:2187 / 2189
页数:2
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