Equilibrium and Kinetic Properties of Methane Hydrate

被引：0

作者：

V. G. Martynets

I. S. Afanas'ev

P. P. Bezverkhii

N. V. Kuskova

E. V. Matizen

机构：

[1] Russian Academy of Sciences,Institute of Inorganic Chemistry, Siberian Division

来源：

Theoretical Foundations of Chemical Engineering | 2002年 / 36卷

关键词：

Experimental Data; Methane; Hydrate; Kinetic Property; Methane Concentration;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

During methane dissolution in water in a closed space, the pressure varies exponentially with time until the formation of methane hydrate. A model of this process is proposed that fits experimental data well. The methane concentration at the onset of hydrate formation is calculated as a function of temperature and pressure.

引用

页码：495 / 499

页数：4

共 18 条

[1] Martynets V.G.(1999)Critical Line of (Xenon + Carbon Dioxide) J. Chem. Thermodyn. 31 191-undefined
[2] Matizen E.V.(1999)Methane Hydrate Formation and Decomposition: Metastability Region and Phase-Equilibrium Curves Khim. Interes. Ust. Razv. 7 643-undefined
[3] Kuskova N.V.(1995)Pressure and Temperature Conditions for Methane Hydrate Dissociation in Sodium Chloride Solutions Geochem. J. 29 325-undefined
[4] Kukarin V.F.(1990)Application of Stokes' Law to Ions in Aqueous Solution J. Phys. Chem. 94 2671-undefined
[5] Bezverkhii P.P.(2000)Mechanisms of Methane Hydrate Crystallization in Semibatic Reactor Ann. N. Y. Acad. Sci. 912 564-undefined
[6] Kuskova N.V.(1990)Effect of Hydrostatic Pressure and Salinity on Gas Hydrates J. Phys. Chem. 94 2652-undefined
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[8] Matizen E.V.(undefined)undefined undefined undefined undefined-undefined
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[10] Iton S.(undefined)undefined undefined undefined undefined-undefined

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