KMg1−xPdxF3 with Perovskite-Like Structures as Precursors for the Catalytic Hydroconversion of CCl2F2 and CHClF2

被引：0
作者：
A. Morato
C. Alonso
F. Medina
J.L. Garreta
J.E. Sueiras
Y. Cesteros
P. Salagre
D. Tichit
B. Coq
机构：
[1] Universitat Rovira i Virgili,Departament d'Enginyeria Química, ETSEQ
[2] Universitat Rovira i Virgili,Departament d'Enginyeria Química, ETSEQ
[3] Universitat Rovira i Virgili,Facultat de Química
[4] Laboratoire de Matériaux Catalytiques et Catalyse en Chimie Organique,undefined
[5] UMR CNRS-ENSCM 5618,undefined
来源：
Catalysis Letters | 2001年 / 77卷
关键词：
perovskite; CFC; palladium catalysts; hydrodechlorination;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Several fluoride type perovskites, with formula KMg1−xPdxF3, have been prepared for the first time. The enlargement of their cell parameters has been associated with the insertion of Pd into the structure. After reduction, these new compounds, when tested in the hydrodechlorination reaction of CCl2F2 and CHClF2, showed higher selectivities to CHClF2 and CH2F2, respectively, than other Pd catalysts supported on KMgF3.
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页码：141 / 146
页数：5
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