Kinetics and mechanism of the catalytic epoxidation of cyclohexene with tert-butyl hydroperoxide in the presence of molybdenum–squarate complex

被引：1
作者：
Encho H. Balbolov
Stefan V. Kotov
Tsonko M. Kolev
Mariana G. Topuzova
机构：
[1] University “Prof. Dr. As. Zlatarov”,
[2] Institute of Organic Chemistry,undefined
[3] Bulgarian Academy of Sciences,undefined
来源：
Reaction Kinetics and Catalysis Letters | 2009年 / 97卷
关键词：
Epoxidation; Cyclohexene; Molybdenum–squarate complex; Catalyst;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The kinetics of the catalytic epoxidation of cyclohexene with tert-butyl hydroperoxide (TBHP) in the presence of a novel molybdenum–squarate complex was studied. Both the kinetics and mechanism of the process were found to be similar to those established with the “classical” homogeneous catalysts for epoxidation.
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页码：51 / 57
页数：6
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