Synthesis and characterization of substituted aminobiphenylglyoximes and their complexes with some transition metals

被引:0
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作者
E. Karapinar
N. Karapinar
E. Özcan
机构
[1] Pamukkale University,Department of Chemistry, Faculty of Arts and Sciences
[2] Pamukkale University,Chemistry Engineering Department, Engineering Faculty
[3] Selcuk University,Department of Chemistry, Faculty of Arts and Sciences
关键词
EtOH; Oxime; Coordination Chemistry; Magnetic Susceptibility Measurement; Mononuclear Complex;
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摘要
In this study, four different new vic-dioximates, [L1H2] N-(4-ethylphenyl)amino-biphenylglyoxime, [L2H2] N-(4-butylphenyl)aminobiphenylglyoxime, [L3H2] N-(4-aminoacetanilide)aminobiphenylglyoxime, and [L4H2] N-(thiazol-2-yl-aminobiphenylglyoxime are synthesized from anti-4′-biphenylchloroglyoxime and the corresponding substituted aromatic amines. The Co(II), Ni(II), and Cu(II) complexes of these ligands are prepared. The structures of these new ligands and their complexes are proposed based upon IR, 1H, and 13C NMR spectral data, mass spectroscopy, magnetic susceptibility measurement, and elemental analyses.
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页码:885 / 890
页数:5
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