Dabco Ammonium Halochromates, C6H14N2+\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$ {\text{C}}_{6} {\text{H}}_{14} {\text{N}}_{2}\,^{ + } $$\end{document}Cr2F2O6-\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$ {\text{Cr}}_{2} {\text{F}}_{2} {\text{O}}_{6}\,^{ - } $$\end{document} (DAXC, X = F, Cl), Reagents for Efficient and Mild Oxidation of Organic Substrates

被引:0
作者
M. K. Mohammadi
机构
[1] Islamic Azad University,Department of Chemistry, Ahvaz Branch
来源
Iranian Journal of Science and Technology, Transactions A: Science | 2018年 / 42卷 / 3期
关键词
Dabco ammonium halochromates; Oxidation; Organic substrates and carbonyl;
D O I
10.1007/s40995-018-0497-9
中图分类号
学科分类号
摘要
New orange solid dabco ammonium halochromates, C6H14N2+\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$ {\text{C}}_{6} {\text{H}}_{14} {\text{N}}_{2}\,^{ + } $$\end{document}Cr2F2O6-\documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$ {\text{Cr}}_{2} {\text{F}}_{2} {\text{O}}_{6}\,^{ - } $$\end{document}, DAXC (X = F, Cl) are easily synthesized by the reaction of dabco (1,4-diaza-bicyclo[2.2.2] octane) with CrO3 in a 1:2 molar ratio in the presence of HF or HCl. Dabco ammonium halochromates(VI) are versatile reagents for the effective and selective oxidation of organic substrates to carbonyl derivatives.
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页码:1185 / 1189
页数:4
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