Binding of gold(iii) with silver(i) dipropyldithiocarbamate: supramolecular self-assembly (role of secondary Au…S and Ag…S bonds) and thermal behavior of the ionic-polymer complex ([Au(S2CNPr2)2][AgCl2])n

被引：0

作者：

E. V. Korneeva

A. I. Smolentsev

O. N. Antzutkin

A. V. Ivanov

机构：

[1] Far-Eastern Branch of the Russian Academy of Sciences,Institute of Geology and Nature Management

[2] Siberian Branch of the Russian Academy of Sciences,Nikolaev Institute of Inorganic Chemistry

[3] Novosibirsk State University,undefined

[4] Luleå University of Technology,undefined

[5] University of Warwick,undefined

来源：

Russian Chemical Bulletin | 2019年 / 68卷

关键词：

dialkyldithiocarbamates; binary complexes; noble metals; gold silver compounds; supramolecular self-assembly; secondary interactions; C MAS NMR spectroscopy; thermal behavior;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The double ionic-polymer complex ([Au(S2CNPr2)2][AgCl2])n (1) was prepared as an individual fixation form of gold(III) from NaCl solutions with silver(I) dipropyldithiocarbamate and was characterized by single-crystal X-ray diffraction and 13C magic-angle spinning (MAS) NMR spectroscopy. The structure of 1 comprises two nonequivalent centrosymmetric complex cations [Au(S2CNPr2)2]+ (A and B) and the discrete linear anion [AgCl2]–. Gold(III) cations are linked by pairs of unsymmetrical secondary Au…S bonds to form linear supramolecular chains (…A…B…)n. Neighboring cations are additionally linked by [AgCl2]– anions via secondary Ag…S and Cl…S bonds, the anions being involved in the overall stabilization of the supramolecular structure. The cation–anion interactions lead to a distortion of the linear configuration of the [AgCl2]– anion. The character of thermolysis of 1 accompanied by quantitative regeneration of bound Au and Ag was established by simultaneous thermal analysis.

引用

页码：40 / 47

页数：7

共 28 条

[1] Binding of gold(III) with silver(I) dipropyldithiocarbamate: supramolecular self-assembly (role of secondary Au•••S and Ag•••S bonds) and thermal behavior of the ionic-polymer complex ([Au(S2CNPr2)2][AgCl2])n
Korneeva, E., V
Smolentsev, A., I
Antzutkin, O. N.
Ivanov, A., V
RUSSIAN CHEMICAL BULLETIN, 2019, 68 (01) : 40 - 47
[2] Species of Gold(III) Binding by Binuclear Zinc Dipropyldithiocarbamate: Supramolecular Self-Organization and Thermal Behavior of Ionic Complexes [Au(S2CNPr2)2]2[ZnCl4] and [Au(S2CNPr2)2]2[AuCl4][AuCl2]
Loseva, O. V.
Rodina, T. A.
Gerasimenko, A. V.
Ivanov, A. V.
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2023, 49 (01) : 10 - 23
[3] Species of Gold(III) Binding by Binuclear Zinc Dipropyldithiocarbamate: Supramolecular Self-Organization and Thermal Behavior of Ionic Complexes [Au(S2CNPr2)2]2[ZnCl4] and [Au(S2CNPr2)2]2[AuCl4][AuCl2]
O. V. Loseva
T. A. Rodina
A. V. Gerasimenko
A. V. Ivanov
Russian Journal of Coordination Chemistry, 2023, 49 : 10 - 23
[4] Double pseudo-polymeric complexes of [Au(S2CNBu2)2][AgCl2] and [Au (S2CNHm)2]3[AgCl2][Ag0.59Au0.41Cl2]2: Preparation, supramolecular self-assembly, thermal behaviour and anti-mycobacterial activity
Korneeva, Eugenia, V
Lutsenko, Irina A.
Zinchenko, Sergey, V
Bekker, Olga B.
Nelyubina, Yulia, V
Ivanov, Alexander, V
INORGANICA CHIMICA ACTA, 2024, 572
[5] Binding of Gold(III) from Solutions by the [Ag6{S2CN(CH2)6}6] Cluster: Synthesis, Thermal Behavior, and Self-Organization of the Supramolecular Structure of the Double Complex [Au{S2CN(CH2)6}2]2[AgCl2]Cl·2CHCl3 (Role of Secondary Au⋅⋅⋅Cl, Ag⋅⋅⋅S, and Cl⋅⋅⋅Cl Interactions)
E. V. Korneeva
E. V. Novikova
O. V. Loseva
A. I. Smolentsev
A. V. Ivanov
Russian Journal of Coordination Chemistry, 2021, 47 : 769 - 779
[6] Binding of Gold(III) from Solutions by the [Ag6{S2CN(CH2)6}6] Cluster: Synthesis, Thermal Behavior, and Self-Organization of the Supramolecular Structure of the Double Complex [Au{S2CN(CH2)6}2]2[AgCl2]Cl.2CHCl3 (Role of Secondary Au....Cl, Ag....S, and Cl...Cl Interactions)
Korneeva, E., V
Novikova, E., V
Loseva, O., V
Smolentsev, A., I
Ivanov, A., V
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2021, 47 (11) : 769 - 779
[7] Chemisorptive Synthesis, Self-Assembly of Complicated 2D and 3D Supramolecular Architectures (Role of Hydrogen Bonds and Secondary Interactions Au•••S and S•••Cl), and Thermal Behavior of Pseudo-Polymeric Gold(III)-Mercury(II) Dibutyldithiocarbamato-Chlorido Complexes
Ivanov, A. V.
Loseva, O. V.
Rodina, T. A.
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2020, 46 (09) : 639 - 652
[8] Chemisorptive Synthesis, Self-Assembly of Complicated 2D and 3D Supramolecular Architectures (Role of Hydrogen Bonds and Secondary Interactions Au···S and S···Cl), and Thermal Behavior of Pseudo-Polymeric Gold(III)–Mercury(II) Dibutyldithiocarbamato-Chlorido Complexes
A. V. Ivanov
O. V. Loseva
T. A. Rodina
Russian Journal of Coordination Chemistry, 2020, 46 : 639 - 652
[9] Binding of Gold(III) from Solutions with Thallium(I) Dibutyldithiocarbamate: Synthesis, Supramolecular Self-Organization, and Thermal Behavior of the Complex ([Au{S2CN(C4H9)2}2][TlCl4])n
Ivanov, A. V.
Bredyuk, O. A.
Loseva, O. V.
RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2018, 88 (07) : 1470 - 1477
[10] Binding of Gold(III) from Solutions with Thallium(I) Dibutyldithiocarbamate: Synthesis, Supramolecular Self-Organization, and Thermal Behavior of the Complex ([Au{S2CN(C4H9)2}2][TlCl4])n
A. V. Ivanov
O. A. Bredyuk
O. V. Loseva
Russian Journal of General Chemistry, 2018, 88 : 1470 - 1477

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