The Confinement Factor: A Thermodynamic Parameter to Characterize Microporous Adsorbents

被引：0
作者：
Joeri F. M. Denayer
Gino V. Baron
机构：
[1] Vrije Universiteit Brussel,Department of Chemical Engineering
来源：
Adsorption | 2005年 / 11卷
关键词：
zeolites; adsorption; enthalpy; entropy; confinement; pore size;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Low coverage adsorption properties of n-alkanes were used to characterize microporous adsorbents. A confinement factor Z, defined as the ratio of the increase of adsorption entropy with carbon number over the increase of adsorption entropy with carbon number, correlates well with the pore size.
引用
收藏
页码：85 / 90
页数：5
相关论文
共 65 条
[1]  
Arik I.C.(2003)undefined Microporous Microp. Mesopor. Mat 60 111-124
[2]  
Denayer J.F.M.(1981)undefined J. Chem. Soc., Faraday Trans. 1 77 897-907
[3]  
Baron G.V.(1961)undefined Trans. Faraday, Soc. 57 999-463
[4]  
Atkinson D.(1956)undefined Proc. Roy. Soc 237A 439-383
[5]  
Curthoys G.(2000)undefined Catal. Rev. –Sci. Eng 42 323-3081
[6]  
Barrer R.M.(1998)undefined J. Phys. Chem. B 10 3077-535
[7]  
Rees L.V.C.(1996)undefined Recl. Trav. Chim. Pays-Bas 115 531-1278
[8]  
Barrer R.M.(1997)undefined J. Phys. Chem. B 101 1273-5419
[9]  
Sutherland J.W.(1997)undefined J. Phys. Chem B 101 5414-961
[10]  
Bond C.G.(1981)undefined J. Catal. 67 218-59
1234567