Analysis of α-alumina samples by mass spectrometry with inductively coupled plasma and laser ablation

被引:0
作者
V. A. Khvostikov
V. K. Karandashev
Zh. P. Burmii
机构
[1] Russian Academy of Sciences,Institute of Microelectronics Technology and High
来源
Inorganic Materials | 2015年 / 51卷
关键词
laser ablation; inductively coupled plasma; mass spectrometry; α-alumina;
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摘要
A procedure for analysis of a-alumina (sapphire, corundum, etc.) samples by mass spectrometry with inductively coupled plasma and laser ablation (LA-ICP-MS) is described. This procedure allows one to determine up to 60 impurity elements with detection limits of 10–7–10–4 wt %. The validity of the results of LA-ICP-MS determination is verified by comparing them to the results obtained using an independent technique that is based on dissolving the samples in a mixture of H2SO4 and H3PO4 with subsequent determination of impurity elements by atomic emission spectrometry and mass spectrometry with inductively coupled plasma.
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页码:1410 / 1415
页数:5
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[1]  
Malyukov S.P.(2010)Techniques for optimizing the fabrication of single crystals of leucosapphire Izv. Yuzhn. Fed. Univ. Tekh. Nauki 7 210-216
[2]  
Nelina S.N.(1990)Determination of titanium, zirconium, molybdenum, and vanadium in highpurity α-alumina Vysokochist. Veshchestva 3 189-197
[3]  
Klunnikova Yu.V.(1996)Determination of Ba, Ca, and Sr in aluminum oxide and aluminum oxide-based single crystals by atomic emission spectrometry J. Anal. Chem. 51 615-618
[4]  
Leikin S.V.(2008)On the potential to use acetylacetonates of metals in the emission spectral analysis of alumina Vestn. Khar’k. Nats. Univ. Khim. 16 155-159
[5]  
Orlova V.A.(1997)Atomic emission spectrum analysis of aluminum oxide using an argon arc plasmatron J. Anal. Chem. 52 1099-1102
[6]  
Il’chenko O.P.(2000)X-ray fluorescence analysis: state-ofthe-art and trends of development (review) Zavod. Lab., Diagn. Mater. 66 3-19
[7]  
Zolotovnitskaya E.S.(2008)X-ray fluorescence analysis in geology: sample preparation and analysis techniques Vestn. Khar’k. Nats. Univ. Khim. 16 39-58
[8]  
Yurchenko O.I.(2009)Geographic typing of gem corundum: a test case from Australia J. Gemmol. 31 203-210
[9]  
Kholin Yu.V.(2001)Quasi ‘non-destructive’ laser ablation-inductively coupled plasma-mass spectrometry fingerprinting of sapphires Spectrochim. Acta, Part B 56 1219-1231
[10]  
Shevtsov N.I.(1998)Effects of gas environment on picosecond laser ablation Appl. Surf. Sci. 127–129 269-273