Synthesis, structure and magnetic properties of a quasi-two-dimensional compound [Cu(C5H4NCOO)2] · 2H2O

被引：0
|
作者：
Jun Hua Luo
Mao Chun Hong
Qian Shi
Yu Cang Liang
Ying Jun Zhao
Rui Hu Wang
Rong Cao
Jia Bao Weng
机构：
[1] Chinese Academy of Sciences,State Key Laboratory of Structure, Fujian Institute of Research on the Structure of Matter
来源：
Transition Metal Chemistry | 2002年 / 27卷
关键词：
Copper; Physical Chemistry; 2H2O; Inorganic Chemistry; Carboxylate;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A new compound [Cu(C5H4NCOO)2] · 2H2O has been prepared. Its structure consists of a chain built from [Cu(C5H4NCOO)2] units, bridged through weak interactions between the copper(II) atoms and the O atoms of the carboxylate groups of a adjacent [Cu(C5H4NCOO)2] units. I.r. spectra, thermal analysis and elemental analysis have been recorded for the complex. Room temperature X-band e.s.r. spectra of powered samples and variable-temperature magnetic susceptibility studies indicate that the compound exhibits a weak ferromagnetic interaction through Cu—O—C—O—Cu pathways.
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收藏
页码：311 / 315
页数：4
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