Development of RuO2/Rutile-TiO2 Catalyst for Industrial HCl Oxidation Process

被引：20
作者：
Kohei Seki
机构：
[1] Sumitomo Chemical Co.,Basic Chemicals Research Laboratory
[2] Ltd.,undefined
来源：
Catalysis Surveys from Asia | 2010年 / 14卷
关键词：
RuO; catalyst; Chlorine recycle; Hydrogen chloride oxidation; Fixed-bed reactor; EXAFS; RuO; /TiO; Rutile TiO;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Sumitomo Chemical has developed a low energy consuming and green process for the catalytic oxidation of HCl to Cl2, especially when compared with the electrolysis process. The RuO2/rutile-TiO2 catalyst has high catalytic activity and thermal stability due to ultra-fine RuO2 crystallites that cover the surface of the TiO2 primary particles with strong interaction. In addition, the silica modified RuO2/rutile-TiO2 catalyst shows higher thermal stability by preventing the RuO2 sintering due to using dispersed SiO2 particles. With these catalysts, high reaction rates required for industrial applications are achieved, even at low temperatures.
引用
收藏
页码：168 / 175
页数：7
相关论文
共 43 条
[1]  
Motupally S(1998)undefined Electrochem Soc Interface 7 32-undefined
[2]  
Mah DT(1991)undefined Shokubai 33 15-undefined
[3]  
Freire FJ(1999)undefined Chem Eng Sci 54 2131-undefined
[4]  
Weidner JW(2008)undefined Angew Chem Int Ed Engl 47 2131-undefined
[5]  
Kiyoura T(2008)undefined J Catal 255 29-undefined
[6]  
Yoshida K(2001)undefined J Catal 203 307-undefined
[7]  
Nishida H(1994)undefined Catal Today 21 49-undefined
[8]  
Mortensen M(1990)undefined J Mater Sci Lett 9 291-undefined
[9]  
Minet RG(1989)undefined Shokubai 31 116-undefined
[10]  
Tsotsis TT(1973)undefined J Catal 29 224-undefined
12345