Electrochemical reduction characteristics and the mechanism of chlorinated hydrocarbons at the copper electrode

被引：3

作者：

Xu W. ^{[1
]}

Gao T. ^{[1
]}

Zhou R. ^{[1
]}

Ma L. ^{[1
]}

机构：

[1] National Engineering Research Center for Urban Pollution Control, Tongji University

来源：

Frontiers of Environmental Science & Engineering in China | 2007年 / 1卷 / 2期

关键词：

Chlorinated hydrocarbons; Copper electrode; Cyclic voltammetry; Electrochemical reduction;

D O I：

10.1007/s11783-007-0036-y

中图分类号：

学科分类号：

摘要：

The electrochemical reduction characteristics of chlorinated hydrocarbons were investigated by cyclic voltammetry technique. The reduction mechanism and activity of the chlorinated hydrocarbons at the copper electrode were explored. The relationship between the structure of chlorinated hydrocarbons and their reductive activity were discussed. The experimental results showed that chlorinated alkanes and a portion of chlorinated aromatic hydrocarbons could be reduced directly at the copper electrode. However, chlorinated aromatic hydrocarbons were not easy to reduce at the copper electrode. The results provided a theoretical basis for the catalyzed iron inner electrolysis method. © Higher Education Press 2007.

引用

页码：207 / 212

页数：5

共 12 条

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