Synthesis and structure of 2-(nitromethylene)-2H-1,4-benzothiazin-3(4H)-one

被引:0
作者
V. M. Berestovitskaya
V. A. Tafeenko
S. V. Makarenko
K. D. Sadikov
I. V. Chernyshev
机构
[1] Gertsen Russian State University,
[2] Lomonosov Moscow State University,undefined
来源
Russian Journal of General Chemistry | 2006年 / 76卷
关键词
Carbonyl; Carbonyl Group; Diffraction Data; Form Layer; Neighboring Layer;
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中图分类号
学科分类号
摘要
A new representative of benzothiazines, (2Z)-2-(nitromethylene)-2H-1,4-benzothiazin-3(4H)-one, was synthesized, and its structure was studied. According to 1H NMR, IR, and UV spectral and X-ray diffraction data, the molecules are planar highly conjugated structures that exist in crystal as centrosymmetric dimers; the latter form layers overlapping with each other and held together by strong π-π interaction between the carbonyl groups of neighboring layers.
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页码:135 / 140
页数:5
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