Polymeric gold(I) diisobutyl dithiophosphate, [Au2{S2P(O-iso-C4H9)2}2]n: Synthesis, supramolecular self-organization (a role of aurophilic interaction), 13C and 31P MAS NMR spectroscopy, and thermal behavior

被引：0
|
作者：
E. V. Korneeva
T. A. Rodina
A. V. Ivanov
A. V. Gerasimenko
A. -C. Larsson
机构：
[1] Russian Academy of Sciences,Institute of Geology and Nature Management, Far East Branch
[2] Amur State University,Institute of Chemistry, Far East Branch
[3] Russian Academy of Sciences,undefined
[4] Luleä University of Technology,undefined
来源：
Russian Journal of Coordination Chemistry | 2014年 / 40卷
关键词：
Gold Atom; Dithiophosphate; Synchronous Thermal Analysis; Aurophilic Interaction; Diisobutyl Dithiophosphinate;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A new polymeric gold(I) diisobutyl dithiophosphate (Dtph), [Au2{S2P(O-iso-C4H9)2}2]n (I), was preparatively obtained and characterized by 13C and 31P MAS NMR spectroscopy and X-ray diffraction (CIF file CCDC no. 977818). Diagrams of the χ2 statistic were constructed from the complete 31P MAS NMR spectra and used to calculate the 31P chemical shift anisotropy (δaniso = δzz − δiso) and the asymmetry parameter η = (δyy − δxx)/(δzz − δiso). The main structural unit of complex I is the noncentrosymmetric dinuclear molecule [Au2{S2P(O-iso-C4H9)2}2], in which the gold atoms are linked by two bridging ligands Dtph. The central cyclic structural fragment of the dimer [Au2S4P2] is additionally stabilized by the intramolecular aurophilic interaction Au⋯Au. Further supramolecular self-organization of the complex involves intermolecular aurophilic bonds Au⋯Au that serve to unite adjacent dinuclear molecules [Au2{S2P(O-iso-C4H9)2}2] with different spatial orientations into the polymer chains ([Au2{S2P(O-iso-C4H9)2}2])n. The thermal behavior of complex I was examined by synchronous thermal analysis under argon. The character of the thermolysis of the complex to reduced metallic gold as a final product was determined.
引用
收藏
页码：748 / 756
页数：8
相关论文
共 50 条
  • [31] Synthesis, supramolecular self-organization, and thermal behavior of the heteropolynuclear complex ([H3O][Au{S2CN(CH2)6}2][Au2{S2CN(CH2)6}4][ZnCl4]2)n
    O. V. Loseva
    T. A. Rodina
    A. I. Smolentsev
    A. V. Ivanov
    Journal of Structural Chemistry, 2014, 55 : 901 - 909
  • [32] Piperazinium dihydrogen phosphate, C4H12N2(H2PO4)2:: Synthesis, 31P CP/MAS NMR, structural and thennal investigations
    Jensen, Torbert R.
    Jorgensen, Jens-Erik
    Hazell, Rita G.
    Jakobsen, Hans J.
    Chevallier, Marie-Agnes
    Jorgensen, Lene
    Wiedermann, Aleksandra
    SOLID STATE SCIENCES, 2007, 9 (01) : 72 - 81
  • [33] Synthesis and multinuclear (1H 13C, 31P) NMR studies of arsocanes substituted with a cyclic dithiophosphate ligand.: Molecular structure of O(CH2CH2S)2AsS2P(OCH2)2CEt2
    García, PGY
    Cruz-Almanza, R
    Hernández-Ortega, S
    Cea-Olivares, R
    REVUE ROUMAINE DE CHIMIE, 2002, 47 (10-11) : 1047 - 1053
  • [34] Three-Dimensional Polymeric Thallium(I) Morpholinedithiocarbamate [Tl2{S2CN(CH2)4O}2] n and Its Capability of Binding Gold(III) from Solutions: Chemisorption Synthesis of a Heteronuclear Gold(III)-Thallium(III) Complex of the Ionic Type, ([Au{S2CN(CH2)4O}2][TlCl4]) n , the Role of Secondary Interactions TlaEuro¦O, TlaEuro¦S, and AuaEuro¦S in the Supramolecular Self-Organization, 13C MAS NMR, and Thermal Behavior
    Bredyuk, O. A.
    Loseva, O. V.
    Ivanov, A. V.
    Gowda, V.
    Antzutkin, O. N.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2017, 43 (10) : 638 - 651
  • [35] Synthesis, Supramolecular Self-Organization, and Thermal Behavior of Gold(III)-Thallium(III) Heteronuclear Complexes ([Au{S2CN(CH3)2}2][TlCl4])2 and ([Au{S2CN(C2H5)2}2][TlCl4]) n
    Ivanov, A. V.
    Bredyuk, O. A.
    Loseva, O. V.
    Antzutkin, O. N.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2016, 61 (06) : 755 - 765
  • [36] Synthesis, Supramolecular Self-Organization, and Thermal Behavior of Gold(III)–Thallium(III) Heteronuclear Complexes ([Au{S2CN(CH3)2}2][TlCl4])2 and ([Au{S2CN(C2H5)2}2][TlCl4])n
    A. V. Ivanov
    O. A. Bredyuk
    O. V. Loseva
    O. N. Antzutkin
    Russian Journal of Inorganic Chemistry, 2016, 61 : 755 - 765
  • [37] A fixation mode of gold from solutions using heterogeneous reaction of cadmium dicyclohexyl dithiophosphate with H[AuCl4]. Structural and (13C, 31P) CP/MAS NMR studies and thermal behaviour of crystalline polymeric gold(I) dicyclohexyl dithiophosphate and bis(dicyclohexylthiophosphoryl) disulphide
    Ivanov, Alexander V.
    Korneeva, Eugenia V.
    Lutsenko, Irina A.
    Gerasimenko, Andrey V.
    Antzutkin, Oleg N.
    Larsson, Anna-Carin
    Sergienko, Valentin I.
    JOURNAL OF MOLECULAR STRUCTURE, 2013, 1034 : 152 - 161
  • [38] Chemisorption Synthesis of the Ion-Polymeric Heteronuclear Gold(III)-Bismuth(III) Complex ([Au{S2CN(C3H7)2}2]3[Bi2Cl9]) n Based on [Bi2{S2CN(C3H7)2}6]: 13C MAS NMR, Supramolecular Structure, and Thermal Behavior
    Ivanov, A. V.
    Gerasimenko, A. V.
    Egorova, I. V.
    Zaeva, A. S.
    Novikova, E. V.
    Rodionova, N. A.
    Gowda, V.
    Antzutkin, O. N.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2018, 44 (08) : 518 - 531
  • [39] Chemisorption Synthesis of the Ion-Polymeric Heteronuclear Gold(III)–Bismuth(III) Complex ([Au{S2CN(C3H7)2}2]3[Bi2Cl9])n Based on [Bi2{S2CN(C3H7)2}6]: 13C MAS NMR, Supramolecular Structure, and Thermal Behavior
    A. V. Ivanov
    A. V. Gerasimenko
    I. V. Egorova
    A. S. Zaeva
    E. V. Novikova
    N. A. Rodionova
    V. Gowda
    O. N. Antzutkin
    Russian Journal of Coordination Chemistry, 2018, 44 : 518 - 531
  • [40] 1-(2′,2′,2′-trifluoroethyl)-4-phosphopyrazoles:: Synthesis and IR, 1H NMR, 13C NMR, 19F NMR, and 31P spectroscopic studies
    Hassen, Z
    Ben Akacha, A
    Hajjem, B
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2003, 178 (11) : 2349 - 2356
12345